HARD
JEE Advanced
IMPORTANT
Earn 100

Outline reasonable mechanisms for each of the following reactions.

Question Image

Important Questions on Carboxylic Acids and Their Derivatives

MEDIUM
JEE Advanced
IMPORTANT
Trimyristin C45H86O6, obtained from coconut oil, when heated with aqueous sodium hydroxide followed by acidification gives glycerol and tetradecanoic acid as the only products. Can you assign a structure to trimyristin?
HARD
JEE Advanced
IMPORTANT

Write stereochemical formula for the compounds A to G

(a) cis-3-Methylcyclopentanol +C6H5COCl[A]refluxOH-[B].

(b) cis-3-Methylcyclopentanol + C6H5SO2Cl[C]DMSOOH-[D]

(c) (R)-2-Bromoheptane + OH-acetone[E]

(d)   (R)-2-Bromoheptane+CH3COONa[F]refluxOH-,H2O[G]

HARD
JEE Advanced
IMPORTANT

Identify the products X, Y and Z in the given reactions:

 

Question Image.

HARD
JEE Advanced
IMPORTANT
An ester (I) with molecular formula C9H10O2 was treated with excess of CH3MgBr and the compound so formed was treated with H2SO4 to give an olefin (II). Ozonolysis of (II) gave a ketone with molecular formula C8H8O which show positive iodoform test. The structure of (I) is:
MEDIUM
JEE Advanced
IMPORTANT

Aspartame, an artificial sweetening agent, has the following structure

Question Image

On hydrolysis with dilute HCl, it will give

MEDIUM
JEE Advanced
IMPORTANT
Which of the following ester can be used as acylating agent in mixed Claisen condensation?
MEDIUM
JEE Advanced
IMPORTANT
In an ester molecule there are three C-O bonds,Question Image What do you expect regarding their relative bond length?