EASY
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Rate of reaction depends upon

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Important Questions on Chemical Kinetics

EASY
In mechanism of any reaction, the step going in the slowest manner is called _____
MEDIUM
 Name the factors that affect the rate of a reaction. Explain in detail.
MEDIUM

Adding surfactants in non polar solvent, the micelles structure will look like

(a)

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(b)

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(c)

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(d)

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EASY
The decomposition of phosphine PH3 on tungsten at low pressure is a first-order reaction. It is because the
MEDIUM

The variation of the rate of an enzyme catalyzed reaction with substrate concentration is correctly represented by graph

(a)
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(b)
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(c)
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(d)
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EASY
Zinc piece and zinc powder are taken in two test tubes and equal amount of dil. HCl is added.
(a) In which test tube does the reaction proceed faster? 
(b) Give reason. 
(c) Give an instance in daily life, where such condition is made use. 
MEDIUM
Two reactions A1 and A2 have identical pre-exponential factors. The activation energy of A1 is more than A2 by 10 kJ mol-1 . If k1 and k2 are the rate constants for reactions A1 and A2, respectively at 300 K, then lnk2k1 is equal to

R=8.314 J mol-1K-1
HARD
On which of the following parameters does the rate constant of a reaction depend?
(i) time, (ii) concentration of reactants, (iii) temperature, and (iv) catalyst
MEDIUM
A reaction is second order with respect to a reactant. How is the rate of reaction affected if the concentration of the reactant is doubled?
EASY
Which one of the factors does not affect rate of the reaction?
HARD

Consider the given plots for a reaction obeying Arrhenius equation (0°C<T<300°C): ( K and Ea are rate constant and activation energy, respectively )

(I) 

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(II) 

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EASY
Mention any two factors which influence the rate of reaction.
HARD
Consider the following reversible reaction:

A g+B gAB g

The activation energy of the backward reaction exceeds that of the forward reaction by 2RT (in  mol-1). If the pre-exponential factor of the forward reaction is 4 times that of the reverse reaction, the absolute value of G  (in J mol-1) for the reaction at 300 K is ____.

(Given; ln2= 0.7,  = 2500 J mol-1 at 300 K and G is the Gibbs energy)
MEDIUM

A sample of milk splits after 60min at 300K and after 40min at 400K when the population of Iactobacillus acidophilus in it doubles. The activation energy (in kJ/mol) for this process is closest to ______________.

Given: R =8.3 J mol-1K-1 , ln32=0.4

HARD
In a bimolecular reaction, the steric factor P was experimentally determined to be 4.5. The correct option(s) among the following is(are)
EASY
How will the rate of reaction be affected when surface area of the reactant is reduced?
MEDIUM
The rate of a gaseous reaction is given by the expression k[A][B]2. If the volume of vessel is reduced to one half of the initial volume, the reaction rate as compared to original rate is
MEDIUM
1 L of 2 M CH3COOH is mixed with 1 L of 3 M C2H5OH to form an ester. The rate of the reaction with respect to the initial rate when each solution is diluted with an equal volume of water will be