Select correct statement about hydrolysis of BCl 3 and NCl 3 :

NCl 3 on hydrolysis gives HOCl but BCl 3 gives HCl

NCl 3 is hydrolysed and gives HOCl but BCl 3 is not hydrolysed

Both NCl 3 and BCl 3 on hydrolysis gives HCl

Both NCl 3 and BCl 3 on hydrolysis gives HOCl

Select correct statement about hydrolysis of BCl 3 and NCl 3 :

NCl 3 on hydrolysis gives HOCl but BCl 3 gives HCl

H 3 BO 3 or B ( OH ) 3 is considered as an acid because its molecule

Accepts OH - from water, releasing a proton

Combines with proton from water molecule

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Select correct statement about hydrolysis of BCl₃ and NCl₃ :

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Important Questions on The p-Block Elements

MEDIUM

Chemistry>Inorganic Chemistry>The p-Block Elements>Group 13 Elements: The Boron Family

The correct option pertaining to varying chemical behaviour of the first member of a group(

s

-and

p

- block elements) compared with the subsequent members of the same group is that they
(A) exhibit the maximum covalency of

4

(B) have less electronegativity
(C) possess large charge to radius ratio

MEDIUM

Chemistry>Inorganic Chemistry>The p-Block Elements>Group 13 Elements: The Boron Family

The stability of +1 oxidation state among

Al, Ga, In

and

Tl

increases in the sequence:

EASY

Chemistry>Inorganic Chemistry>The p-Block Elements>Group 13 Elements: The Boron Family

H_{3} {BO}_{3}

B (OH)_{3}

is considered as an acid because its molecule

MEDIUM

Chemistry>Inorganic Chemistry>The p-Block Elements>Group 13 Elements: The Boron Family

Identity the incorrect statement in case of diborane structure

EASY

Chemistry>Inorganic Chemistry>The p-Block Elements>Group 13 Elements: The Boron Family

The correct statements among I to III regrading group 13 element oxides are,
(I) Boron trioxide is acidic.
(II) Oxides of aluminum and gallium are amphoteric.
(III) Oxides of indium and thallium are basic.

EASY

Chemistry>Inorganic Chemistry>The p-Block Elements>Group 13 Elements: The Boron Family

The highest

E^{0}

(in

V

) value for

M^{+} \to M

among the group

13

elements is

EASY

Chemistry>Inorganic Chemistry>The p-Block Elements>Group 13 Elements: The Boron Family

Given below are two statements: one is labelled as Assertion $A$ and the other is labelled as Reason $R$ .

Assertion $A :$ In $T l I_{3},$ isomorphous to ${CsI}_{3}$ , the metal is present in $+ 1$ oxidation state.

Reason $R :$ $T l$ metal has fourteen $f$ electrons in its electronic configuration.

In the light of the above statements, choose the most appropriate answer from the options given below:

MEDIUM

Chemistry>Inorganic Chemistry>The p-Block Elements>Group 13 Elements: The Boron Family

Given below are two statements: one is labelled as Assertion $A$ and the other is labelled as Reason $R$

Assertion $A$ : Boron is unable to form ${BF}_{6}^{3 -}$

Reason $R$ : Size of $B$ is very small.

In the light of the above statements, choose the correct answer from the options given below

EASY

Chemistry>Inorganic Chemistry>The p-Block Elements>Group 13 Elements: The Boron Family

A group 13 element

^{'} X^{'}

reacts with chlorine gas to produce a compound

{XCl}_{3} . {XCl}_{3}

is electron deficient and easily reacts with

{NH}_{3} to form {Cl}_{3} X \leftarrow {NH}_{3}

adduct; however,

{XCl}_{3}

does not dimerize. X is:

HARD

Chemistry>Inorganic Chemistry>The p-Block Elements>Group 13 Elements: The Boron Family

Choose the correct stability order of group

13

elements in their

+ 1

oxidation state.

MEDIUM

Chemistry>Inorganic Chemistry>The p-Block Elements>Group 13 Elements: The Boron Family

In the following reaction sequence, the compound

C

Al + N_{2} \overset{Δ}{⟶} (A) \overset{H_{2} O}{⟶} B (ppt) + C (g)

EASY

Chemistry>Inorganic Chemistry>The p-Block Elements>Group 13 Elements: The Boron Family

Which of these statements is not true ?

MEDIUM

Chemistry>Inorganic Chemistry>The p-Block Elements>Group 13 Elements: The Boron Family

The type of hybridization of Boron in diborane is _____

MEDIUM

Chemistry>Inorganic Chemistry>The p-Block Elements>Group 13 Elements: The Boron Family

A metal

(X)

dissolves both in dilute

H C l

and dilute

N a O H

to liberate

H_{2} .

Addition of

N H_{4} C l

and excess

N H_{4} O H

to an

H C l

solution of

X

produces

Y

as a precipitate.

Y

is also produced by adding

N H_{4} C l

to the

N a O H

solution of

X .

The species

X

and

Y,

respectively, are

EASY

Chemistry>Inorganic Chemistry>The p-Block Elements>Group 13 Elements: The Boron Family

Which of the following complex ions does not exist?

EASY

Chemistry>Inorganic Chemistry>The p-Block Elements>Group 13 Elements: The Boron Family

Which one among the following statements is correct about a solution of borax in water?

EASY

Chemistry>Inorganic Chemistry>The p-Block Elements>Group 13 Elements: The Boron Family

Which one of the following elements is unable to form

{MF}_{6}^{3 -}

ion?

MEDIUM

Chemistry>Inorganic Chemistry>The p-Block Elements>Group 13 Elements: The Boron Family

Sodium borohydride upon treatment with iodine produces a Lewis acid

(X),

which on heating with ammonia produces a cyclic compound

(Y)

and a colorless gas

(Z) . X, Y

and

Z

are

MEDIUM

Chemistry>Inorganic Chemistry>The p-Block Elements>Group 13 Elements: The Boron Family

When metal

M

is treated with

NaOH

, a white gelatinous precipitate

X

is obtained, which is soluble in excess of

NaOH

. Compound

X

when heated strongly gives an oxide which is used in chromatography as an adsorbent. The metal

M

EASY

Chemistry>Inorganic Chemistry>The p-Block Elements>Group 13 Elements: The Boron Family

The molecule which is NOT hydrolysed by water at

25^{o} C

Select correct statement about hydrolysis of BCl3 and NCl3 :

Important Questions on The p-Block Elements

Learn and Prepare for any exam you want !

Select correct statement about hydrolysis of BCl₃ and NCl₃ :