MEDIUM
JEE Main
IMPORTANT
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Spin only magnetic moment of an octahedral complex of Fe2+ in the presence of a strong field ligand in BM is:

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Important Questions on Coordination Compounds

MEDIUM
JEE Main
IMPORTANT
Which one of the following species doesn't have a magnetic moment of 1.73BM, (spin only value)?
EASY
JEE Main
IMPORTANT
An aqueous solution of NiCl2 was heated with excess sodium cyanide in presence of strong oxidizing agent to form Ni(CN)62-. The total change in number of unpaired electrons on metal centre is ___________.
MEDIUM
JEE Main
IMPORTANT
The correct order of intensity of colors of the compounds is:
HARD
JEE Main
IMPORTANT

Simplified absorption spectra of three complexes ((i) and (ii) and (iii)) of M+n ion are provided below; their λmax values are marked as A, B and C respectively. The correct match between the complexes and their λmax values is:

Question Image

(i) M(NCS)6(-6+n)
(ii) MF6(-6+n)
(iii) MNH36n+

HARD
JEE Main
IMPORTANT
Consider that d6 metal ion M2+ forms a complex with aqua ligands, and the spin only magnetic moment of the complex is 4.90BM. The geometry and the crystal field stabilization energy of the complex is :
MEDIUM
JEE Main
IMPORTANT

For octahedral MnII and tetrahedral NiII complexes, consider the following statements :

(I) both the complexes can be high spin.

(II) NiII complex can very rarely be of low spin.

(III) with strong field ligands, MnII complexes can be low spin.

(IV) aqueous solution of MnII ions is yellow in color.

The correct statements are :

MEDIUM
JEE Main
IMPORTANT
The oxidation states of iron atoms in compounds AB and C, respectively, are x, y and z. Then sum of x, y and z is ........... Na4FeCN5NOSANa4FeO4BFe2CO9C