EASY
Earn 100

State kohlraush law of independent migration of ions. Mention one application of the law?

Important Questions on Electrochemistry

EASY
Λm0 values for NaCl,HCl and CH3COONa are 126.4 S cm2 mol-1, 425.9 S cm2 mol-1 and 91.0 S cm2 mol-1 respectively. Λm0 value for CH3COOH is
MEDIUM
λ°m for NH4Cl, NaOH and NaCl are 130, 248 and 126. 5 ohm-1em2mo-1 respectively. The λ°m NH4OH will be,
MEDIUM
Given λ°Mg2+=106 S cm2 mole-1, λ°SO42-=160 S cm2 mole-1. The value of λ°MgSO4 (in S cm2 mole-1)  is
MEDIUM

The molar conductivity of 0.007 M acetic acid is 20 S cm2 mol-1. What is the dissociation constant of acetic acid? Choose the correct option.

λH+=350 S cm2 mol-1λCH3COO-=50 S cm2 mol-1

HARD
State and explain kohlrausch's law of independent migration of ions.
MEDIUM
State Kohlrausch law of independent migration of ions. How is the law used to determine the degree of dissociation of a weak electrolyte?
MEDIUM
Why can limiting molar conductivity of CH3COOH  not be determined experimentally ?
 
MEDIUM
The limiting molar conductivities of NaI,NaNO3 and AgNO3 are 12.7,12.0 and 13.3 mSm2 mol-1, respectively (all at 25 °C). The limiting molar conductivity of AgI at this temperature is____mSm2 mol-1.
EASY
The specific conductance K of 0.02 M aqueous acetic acid solution at 298 K is 1.65×10-4Scm-1. The degree of dissociation of acetic acid is

[Given: equivalent conductance at infinite dilution of H+=349.1Scm2mol-1 and CH3COO-=40.9Scm2  mol-1 ]
MEDIUM
Ionic mobility of Ag+ is λAg+=5×10-1 ohm-1 cm2 eq-1
EASY

The molar conductance of NaCl, HCl and CH3COONa at infinite dilution are 126.45, 426.16 and 91.0 Scm2 mol-1 respectively. The molar conductance of CH3COOH at infinite dilution is. Choose the right option for your answer.

EASY
What is meant by 'limiting molar conductivity' 
HARD
Explain Kohlrausch law. Write in brief two applications of this law.
HARD
Λ°m for NaCl, HCl and NaAc are 126.4, 425.9 and 91.05 cm2mol-1respectively. Calculate Λ°m for HAc.
MEDIUM
0.002M solution of a weak acid has an equivalent conductance (Λ)60ohm-1 cm2eq-1. What will be the pH ? (Given : Λ°=400ohm-1 cm2eq-1 ]
EASY
If the molar conductivities in S cm2 mol-1 of NaCl, KCl and NaOH  at infinite dilution are 126 and 150 and 250 respectively, the molar conductivity of KOH in S cm2 mol-1 is -
HARD
mo for NaCl,HCl and NaA are 126.4,425.9 and 100.5Scm2mol-1 respectively. If the conductivity of 0.001MHA is 5×10-5 S cm-1, degree of dissociation of HA is