EASY
Earn 100

Statement = CP-CV=R for an ideal gas

Explanation =UVT=0 for an ideal gas.

50% studentsanswered this correctly

Important Questions on Thermodynamics

EASY
Which of the following relation is not correct?
MEDIUM
A piece of metal weighing 100 g is heated to 80°C and dropped into 1 kg of cold water in an insulated container at 15°C. If the final temperature of the water in the container is 15.69°C, the specific heat of the metal in J/g°C. is
HARD

The molar heat capacity for an ideal gas at constant pressure is 20.785 J K-1 mol-1. The change in internal energy is 5000 J upon heating it from 300 K to 500 K. The number of moles of the gas at constant volume is____

(Given: R=8.314 J K-1 mol-1)

EASY
Which of the following process best describes atomization of CH4g?
EASY
At constant pressure, the heat of formation of a compound is not dependent on temperature, when
HARD

The specific heat of a certain substance is 0.86 J g-1 K-1. Assuming ideal solution behavior, the energy required (in J) to heat 10 g of 1 molal of its aqueous solution from 300 K to 310 K is closest to :

[Given: molar mass of the substance =58 g mol-1; specific heat of water =4.2 J g-1 K-1]

MEDIUM

A fish swimming in water body when taken out from the water body is covered with a film of water of weight 36 g. When it is subjected to cooking at 100 °C, then the internal energy for vaporization in kJmol-1 is integer]

[Assume steam to be an ideal gas. Given ΔvapH for water at 373 K and 1 bar is 41.1 kJ mol-1:R=8.31 J K-1 mol-1]

EASY
The work done during combustion of 9×10-2 kg of ethane, C2H6(g) at 300 K is (Given R=8.314 JK1mol1 , atomic mass C=12,H=1 )
EASY

The quantity of heat (in J) required to raise the temperature of 1.0 kg of ethanol from 293.45 K to the boiling point and then change the liquid to vapor at that temperature is closest to [Given, boiling point of ethanol 351.45 K. Specific heat capacity of liquid ethanol 2.44 J g-1 K-1. Latent heat of vaporisation of ethanol 855 Jg-1 ]

 

EASY
The difference between C¯p and C¯V is C¯p and C¯V signify molar quantities]
HARD
An ideal gas undergoes isothermal compression from 5 m3 to 1 m3 against a constant external pressure of 4 N m-2. The heat released in this process is 24 J mol-1K-1 and is used to increase the pressure of 1 mole of Al. The temperature of Al increases by:
MEDIUM
At constant volume, 4 mol of an ideal gas when heated from 300K to 500K changes its internal energy by 5000J. The molar heat capacity at constant volume is ________
MEDIUM

The combination of plots which does not represent isothermal expansion of an ideal gas is

(A) Question Image

(B) Question Image

C Question Image

(D) Question Image

MEDIUM
When a 60 W electric heater is immersed in a gas for 100 s in a constant volume container with adiabatic walls, the temperature of the gas rises by 5°C. The heat capacity of the given gas is JK-1 (Nearest integer)
HARD
A reversible cyclic process for an ideal gas is shown below. Here, P, V, and T are pressure, volume and temperature, respectively. The thermodynamic parameters q, w, H and U are heat, work, enthalpy and internal energy, respectively.

Question Image

The correct option(s) is (are)
EASY
If 100 mole of H2O2 decompose at 1 bar and 300 K, the work is done (kJ) by one mole of O2(g) as it expands against 1 bar pressure is:

2H2O2l2H2Ol+O2(g)

R=8.3 J K-1 mol-1
EASY
An ideal gas undergoes isothermal expansion at constant pressure. During the process:
MEDIUM

200 mL of 0.2 M HCl is mixed with 300 mL of 0.1 M NaOH. The molar heat of neutralization of this reaction is -57.1 kJ. The increase in temperature in C of the system on mixing is x×10-2. The value of x is (Nearest integer)

[Given: Specific heat of water =4.18 J g-1 K-1 

Density of water=1.00 g cm-3]

(Assume no volume change on mixing)

MEDIUM
Two moles of helium gas is mixed with three moles of hydrogen molecules (taken to be rigid). What is the molar specific heat of mixture at constant volume? R=8.3 J/mol K
MEDIUM
X g of ice at 0oC is added to 340g of water at 20oC . The final temperature of the resultant mixture is 5oC . The value of X (in g) is closest to

[Heat of fusion of ice =333 J/g ; Specific heat of water =4.184 J/g.K ]