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Statement 1 : Tertiary amine is less basic than secondary amine in aqueous
solution.

Statement 2 : Over crowding due to I+ effect of three alkyl groups increases strain.

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Important Questions on Amines

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Among the following compounds, the increasing order of their basic strength is:

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Chemistry>Organic Chemistry>Amines>Chemical Properties of Amines
The amine which reacts with p-toluene sulphonyl chloride to give a clear solution which on acidification gives insoluble compound is
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A mixture containing the following four compounds is extracted with 1 M HCl. The compound that goes to aqueous layer is:
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Chemistry>Organic Chemistry>Amines>Chemical Properties of Amines

In the reaction sequence
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X and Y are, respectively,

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The major product of the following reaction is:

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The compound  X C7H9N reacts with benzenesulfonyl chloride to give  Y C13H13NO2S which is insoluble in alkali. The compound X is
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Chemistry>Organic Chemistry>Amines>Chemical Properties of Amines
The nitrosation of N,N-dimethylaniline takes place through the attack of electrophile:
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The test to distinguish primary, secondary and tertiary amines is:
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Chemistry>Organic Chemistry>Amines>Chemical Properties of Amines
The following reaction

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Is known by the name:
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Chemistry>Organic Chemistry>Amines>Chemical Properties of Amines
The gas leaked from a storage tank of the Union Carbide plant in Bhopal gas tragedy was :
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Chemistry>Organic Chemistry>Amines>Chemical Properties of Amines
The major product of the reaction is
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What will be the major product in the following mononitration reaction?

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On heating an aliphatic primary amine with chloroform and ethanolic potassium hydroxide, the organic compound formed is :
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Aniline reacts with excess Br2/H2O to give the major product
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The final product formed when methylamine is treated with NaNO 2 and HCl followed by hydrolysis is:
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Aniline dissolved in dilute HCl is reacted with sodium nitrite at 0°C. This solution was added dropwise to a solution containing an equimolar mixture of aniline and phenol in dilute HCl. The structure of the major product is
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Chemistry>Organic Chemistry>Amines>Chemical Properties of Amines
The major product in the following reaction is:
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Chemistry>Organic Chemistry>Amines>Chemical Properties of Amines
Which of the following compounds will form significant amount of meta product during mono-nitration reaction?
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Chemistry>Organic Chemistry>Amines>Chemical Properties of Amines

The major product obtained in the following reaction is:
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Chemistry>Organic Chemistry>Amines>Chemical Properties of Amines

The major product formed in the reaction given below will be :

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