MEDIUM
JEE Main
IMPORTANT
Earn 100

The correct order of intensity of colors of the compounds is:

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Important Questions on Coordination Compounds

HARD
JEE Main
IMPORTANT

Simplified absorption spectra of three complexes ((i) and (ii) and (iii)) of M+n ion are provided below; their λmax values are marked as A, B and C respectively. The correct match between the complexes and their λmax values is:

Question Image

(i) M(NCS)6(-6+n)
(ii) MF6(-6+n)
(iii) MNH36n+

HARD
JEE Main
IMPORTANT
Consider that d6 metal ion M2+ forms a complex with aqua ligands, and the spin only magnetic moment of the complex is 4.90BM. The geometry and the crystal field stabilization energy of the complex is :
MEDIUM
JEE Main
IMPORTANT

For octahedral MnII and tetrahedral NiII complexes, consider the following statements :

(I) both the complexes can be high spin.

(II) NiII complex can very rarely be of low spin.

(III) with strong field ligands, MnII complexes can be low spin.

(IV) aqueous solution of MnII ions is yellow in color.

The correct statements are :

MEDIUM
JEE Main
IMPORTANT
The oxidation states of iron atoms in compounds AB and C, respectively, are x, y and z. Then sum of x, y and z is ........... Na4FeCN5NOSANa4FeO4BFe2CO9C
MEDIUM
JEE Main
IMPORTANT
An octahedral complex with molecular composition M.5NH3.Cl.SO4 has two isomers, A and B. The solution of A gives a white precipitate with AgNO3 solution and the solution of B gives white precipitate with BaCl2 solution .The type of isomerism exhibited by the complex is :
EASY
JEE Main
IMPORTANT
Amongst the following, identify the species with an atom in +6 oxidation state.
HARD
JEE Main
IMPORTANT
Nickel (Z=28) combines with a uninegative monodentate ligand to form a diamagnetic complex NiL 4 2 . The hybridisation involved and the number of unpaired electrons present in the complex are respectively: