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The electrophile, E   attacks the benzene ring to generate the intermediate σ -complex as shown in the following. Which σ - complex has lowest energy ?

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Important Questions on Hydrocarbons

MEDIUM
Which of the following can be used as the halide component for Friedel-Crafts reaction?
EASY
The major product obtained in the reaction of toluene with 1-brome-2-methyl propane in the presence of anhydrous AlCl3 is
MEDIUM

Among the following, the reaction that proceeds through an electrophilic substitution, is:

EASY
Some meta-directing substituents in aromatic substitution are given. Which one is most deactivating?
EASY

In the following reactions

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X and Y, respectively, are:

MEDIUM
The increasing order of the reactivity of the following compounds towards electrophilic aromatic substitution reactions is:
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EASY

The compounds A and B in the following reaction are, respectively:

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MEDIUM

The major product of the following reaction is:
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MEDIUM
The increasing order of reactivity of the following compounds towards aromatic electrophilic substitution reaction is:
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EASY
Aromatic electrophilic substitution reaction that is reversible is
MEDIUM

The major product obtained in the given reaction is:

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EASY
Which of the following compounds will not undergo Friedel Crafts reaction with benzene?
MEDIUM
p-Hydroxybenzophenone upon reaction with bromine in carbon tetrachloride gives:
HARD
Consider the following reactions:
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Which of these reactions are possible?
MEDIUM
Which product is formed when the following compound is treated with Br2 in the presence of FeBr3?
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EASY
The oxidation of benzene by V2O5 in the presence of air produces:
EASY

The correct IUPAC name of the following compound is:

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MEDIUM
Arrange the following compounds in order of decreasing acidity :
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