EASY

Earn 100

The elevation of boiling point of $0.10 m$ aqueous ${CrCl}_{3} {xNH}_{3}$ solution is two times that of $0.05 m$ aqueous ${CaCl}_{2}$ , solution. The value of $x$ is..........

[Assume $100 %$ ionisation of the complex and ${CaCl}_{2}$ , coordination number of $Cr$ as $6$ , and that all ${NH}_{3}$ molecules are present inside the coordination sphere]

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Important Questions on Solutions

MEDIUM

Chemistry>Physical Chemistry>Solutions>Elevation in Boiling Point

The boiling point of

0.2 m o l k g^{- 1}

solution of X in water is greater than equimolal solution of Y in water. Which one of the following statements is true in this case?

EASY

Chemistry>Physical Chemistry>Solutions>Elevation in Boiling Point

The boiling point of

0.001 M

aqueous solutions of

NaCl, {Na}_{2} {SO}_{4}, K_{3} {PO}_{4}

and

{CH}_{3} COOH

should follows the order.

HARD

Chemistry>Physical Chemistry>Solutions>Elevation in Boiling Point

If a compound

AB

dissociates to the extent of

75 %

in an aqueous solution, the molality of the solution which shows a

2.5 K

rise in the boiling point of the solution is ___ molal. (Rounded-off to the nearest integer)

[K_{b} = 0.52 K kg {mol}^{- 1}]

HARD

Chemistry>Physical Chemistry>Solutions>Elevation in Boiling Point

${AB}_{2}$ is $10 %$ dissociated in water to $A^{2 +}$ and $B^{-}$ . The boiling point of $10.0$ molal aqueous solution of ${AB}_{2}$ is-- ${}^{\circ}C$ . (Round off to the Nearest Integer).

[Given : Molal elevation constant of water $K_{b} = 0.5 K kg {mol}^{- 1}$ boiling point of pure water $= 100 ° C$ ]

MEDIUM

Chemistry>Physical Chemistry>Solutions>Elevation in Boiling Point

An aqueous solution freezes at

272.4 K

, while pure water freezes at

273 K

, given

K_{f} = 1.86 K kg {mol}^{- 1}

, and

K_{b} = 0.512 K kg {mol}^{- 1};

the molality of solution and boiling point of solution respectively will be -

EASY

Chemistry>Physical Chemistry>Solutions>Elevation in Boiling Point

Molal elevation constant is the elevation in boiling point produced by

EASY

Chemistry>Physical Chemistry>Solutions>Elevation in Boiling Point

The boiling point (in

{}^{\circ}C

) of

0.1

molal aqueous solution of

{CuSO}_{4} . 5 H_{2} O

1

bar is closest to: [Given: Ebullioscopic (molal boiling point elevation) constant of water,

K_{b} = 0.512 K {kgmol}^{- 1}]

EASY

Chemistry>Physical Chemistry>Solutions>Elevation in Boiling Point

When

3.00 g

of a substance

X

' is dissolved in

100 g

{CCl}_{4}

, it raises the boiling point by

0.60 K

. The molar mass of the substance '

X^{'}

is ___ g

{mol}^{- 1}

.
(Nearest integer).
[Given

K_{b}

for

{CCl}_{4}

5.0 K kg {mol}^{- 1}]

MEDIUM

Chemistry>Physical Chemistry>Solutions>Elevation in Boiling Point

Solute

' X'

dimerises in water to the extent of

80 %

2.5 g

' X'

100 g

of water increases the boiling point by

0.3 ° C

. The molar mass of

' X'

[K_{b} = 0.52 K {kgmol}^{- 1}]

MEDIUM

Chemistry>Physical Chemistry>Solutions>Elevation in Boiling Point

180 g

of glucose,

C_{6} H_{12} O_{6}

is dissolved in

1 kg

of water in a saucepan. At what temperature the solution will boil at

1.013

bar?

(K_{b}

for water is

0.52 K kg {mol}^{- 1})

MEDIUM

Chemistry>Physical Chemistry>Solutions>Elevation in Boiling Point

A solute $A$ dimerizes in water. The boiling point of a $2$ molal solution of $A$ is $100.52 {}^{\circ}C$ . The percentage association of $A$ is ___ .
(Round off to the Nearest integer)

Use : $K_{b}$ for water $= 0.52 K kg {mol}^{- 1}$

Boiling point of water $= 100 ° C$

EASY

Chemistry>Physical Chemistry>Solutions>Elevation in Boiling Point

1 g

of a non-volatile non-electrolyte solute is dissolved in

100 g

of two different solvents

A

and B whose ebullioscopic constants are in the ratio of

1 : 5

. The ratio of the elevation in their boiling points,

\frac{∆ T_{b} (A)}{∆ T_{b} (B)}

, is: (assuming they have the same molar mass)

EASY

Chemistry>Physical Chemistry>Solutions>Elevation in Boiling Point

Which of the following aqueous solution will have the boiling point

102.2 ° C ?

The molal elevation constant for water is

2.2 K kg {mol}^{- 1} .

MEDIUM

Chemistry>Physical Chemistry>Solutions>Elevation in Boiling Point

1

molal aqueous solution of an electrolyte

A_{2} B_{3}

60 %

ionised. The boiling point of the solution at

1 atm

is _____

K

. (Rounded-off to the nearest integer) [Given

K_{b}

for

(H_{2} O) = 0.52 K kg {mol}^{- 1}

]

MEDIUM

Chemistry>Physical Chemistry>Solutions>Elevation in Boiling Point

The boiling point of a sugar solution when

3.42 g

of sugar is dissolved in

40 g

water is

(K_{b} = 0.52 {}^{\circ}C)

HARD

Chemistry>Physical Chemistry>Solutions>Elevation in Boiling Point

1.22 g

of an organic acid is separately dissolved in

100 g

of benzene

(K_{b} = 2.6 K kg {mol}^{- 1})

and

100 g

of acetone

(K_{b} = 1.7 K kg {mol}^{- 1}) .

The acid is known to dimerize in benzene but remain as a monomer in acetone. The boiling point of the solution in acetone increases by

0.17 ° C .

The increase in boiling point of solution in benzene in

{}^{\circ}C

x \times 10^{- 2} .

The value of

x

is (Nearest integer)
[Atomic mass :

C = 12.0, H = 1.0, O = 16.0

]

MEDIUM

Chemistry>Physical Chemistry>Solutions>Elevation in Boiling Point

What will be the boiling point of

30 g

benzene containing

0.75 g

of benzoic acid which undergoes

75 %

dimerization? Boiling point of pure benze

= 80.1 ° C

and

K_{b} = 2.53 {Kmol}^{- 1} kg

MEDIUM

Chemistry>Physical Chemistry>Solutions>Elevation in Boiling Point

The elevation in the boiling point of an aqueous solution of

NaCl

0.01 ° C

. If its van't Hoff factor is

1.92,

the molality of

NaCl

solution is ___

(K_{b}

for water

= 0.52 K kg {mol}^{- 1})

EASY

Chemistry>Physical Chemistry>Solutions>Elevation in Boiling Point

The elevation of boiling point of

0.10 m

aqueous

{CrCl}_{3} . {xNH}_{3}

solution is two times that of

0.05 m

aqueous

{CaCl}_{2}

solution. The value of

x

\dots \dots \dots \dots . .

[Assume

100 %

ionisation of the complex and

{CaCl}_{2},

coordination number of

Cr

6,

and that all

{NH}_{3}

molecules are present inside the coordination sphere]

EASY

Chemistry>Physical Chemistry>Solutions>Elevation in Boiling Point

1 m o l

N a C l

solute is dissolved in

1 k g

of water, at what temperature will water boil at

1.013

bar?

(K_{b} o f w a t e r i s 0.52 K k g m o l^{- 1})

Important Questions on Solutions

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