HARD
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The equivalent conductance (Λ) of an aqueous solution of a strong electrolyte of concentration [X] is given by Λ=Λ0-Ac1/2, where A is a constant and c is the concentration of the electrolyte. The specific conductance κ (with Λ=1000κ/c ) of NaCl and KCl salt solutions (aqueous) are plotted against c. The correct figure is: (The plots are not drawn to scale.)

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Important Questions on Electrochemistry

EASY
_____ are the reason for the electrical conductance of sodium chloride in molten state.
EASY
Define the following terms: Specific conductance.
HARD
mo for NaCl,HCl and NaA are 126.4,425.9 and 100.5Scm2mol-1 respectively. If the conductivity of 0.001MHA is 5×10-5 S cm-1, degree of dissociation of HA is
MEDIUM
An electrolyte of a polymer-salt complex of poly (ethylene oxide) - LiCF3SO3 is shaped into a free standing circular film of 20 mm diameter and a thickness of 20μm.When it is sandwiched between 2 stainless steel circular electrodes of the same diameter, this cell exhibits a conductance of 3145 S.What is the specific conductivity of the electrolyte?
EASY
If the molar conductivities in S cm2 mol-1 of NaCl, KCl and NaOH  at infinite dilution are 126 and 150 and 250 respectively, the molar conductivity of KOH in S cm2 mol-1 is -
EASY
The value of electrical resistance at super conductivity state is
EASY
If the conductivity of mercury at 0°C is 1.07×106 S m-1 and the resistance of a cell containing mercury is 0.243Ω, then the cell constant of the cell is x×104 m-1. The value of x is ______ . (Nearest integer)
MEDIUM
The molar conductivity of a 0.5 mol dm-3 solution of AgNO3 with electrolytic conductivity of 5.76×10-3 S cm-1 at 298 K
EASY
Amongst the following, the form of water with the lowest ionic conductance at 298K is:
EASY
The specific conductance K of 0.02 M aqueous acetic acid solution at 298 K is 1.65×10-4Scm-1. The degree of dissociation of acetic acid is

[Given: equivalent conductance at infinite dilution of H+=349.1Scm2mol-1 and CH3COO-=40.9Scm2  mol-1 ]
MEDIUM
Which of the following solutions of KCl will have highest specific conductance?
MEDIUM
Give a reason for the following.
Conductivity of dilute hydrochloric acid is greater than that of acetic acid.
MEDIUM
The molar conductivities of HCl, NaCl, CH3COOH and CH3COONa at infinite dilution follow the order
MEDIUM
The electrical resistance of a column of 0.05MNaOH solution of diameter 1 cm and length 50 cm is 6.5×103ohm. Its molar conductivity will be
MEDIUM
Let CNaCl and CBaSO4, be the conductances (in S) measured for saturated aqueous solutions of NaCl and BaSO4 respectively, at a temperature T. Which of the following is false?
EASY
The decreasing order of electrical conductivity of the following aqueous solutions is:
A 0.1 M Formic acid,
B 0.1 M Acetic acid,
C 0.1 M Benzoic acid.