The correct statement about the magnetic properties of [Fe(CN) 6 ] 3- and [FeF 6 ] 3- is : (Z = 26).

[Fe(CN) 6 ] 3- is paramagnetic, [FeF 6 ] 3- is diamagnetic.

[Fe(CN) 6 ] 3- is diamagnetic, [FeF 6 ] 3- is paramagnetic.

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The observed magnetic moment of the complex $[Mn (NCS)_{6})]^{x -}$ is $6.06 BM$ . The numerical value of $x$ is

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Important Questions on Coordination Compounds

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Chemistry>Inorganic Chemistry>Coordination Compounds>VBT for Bonding in Coordination Compounds

The difference in the number of unpaired electrons of a metal ion in its high-spin and low-spin octahedral complexes is two. The metal ion is:

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Chemistry>Inorganic Chemistry>Coordination Compounds>VBT for Bonding in Coordination Compounds

Ni {(CO)}_{4}

is:

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Chemistry>Inorganic Chemistry>Coordination Compounds>VBT for Bonding in Coordination Compounds

The correct statement about the magnetic properties of [Fe(CN)₆]^3- and [FeF₆]^3- is : (Z = 26).

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Chemistry>Inorganic Chemistry>Coordination Compounds>VBT for Bonding in Coordination Compounds

The metal's

d -

orbitals that are directly facing the ligands in

K_{3} [Co {(CN)}_{6}]

are:

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Chemistry>Inorganic Chemistry>Coordination Compounds>VBT for Bonding in Coordination Compounds

The hybridization involved in complex

{[N i {(C N)}_{4}]}^{2 -}

is: (Atomic number of Ni = 28)

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Chemistry>Inorganic Chemistry>Coordination Compounds>VBT for Bonding in Coordination Compounds

The pair having the same magnetic moment is:

[A t . N o . : C r = 24, M n = 25, F e = 26, C o = 27]

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Chemistry>Inorganic Chemistry>Coordination Compounds>VBT for Bonding in Coordination Compounds

The spin only magnetic moment of

{[{ZCl}_{4}]}^{2 -}

3.87 BM

where

Z

is:

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Chemistry>Inorganic Chemistry>Coordination Compounds>VBT for Bonding in Coordination Compounds

The species that has a spin-only magnetic moment of

5.9 BM,

is :
(

T_{d} =

tetrahedral)

HARD

Chemistry>Inorganic Chemistry>Coordination Compounds>VBT for Bonding in Coordination Compounds

The geometries of the ammonia complexes of

N i^{2 +}, P t^{2 +} a n d Z n^{2 +}

respectively, are :

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Chemistry>Inorganic Chemistry>Coordination Compounds>VBT for Bonding in Coordination Compounds

Which one of the following has square planar structure?

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Chemistry>Inorganic Chemistry>Coordination Compounds>VBT for Bonding in Coordination Compounds

The correct statements among I to III are:
(I) Valence bond theory cannot explain the color exhibited by transition metal complexes.
(II) Valence bond theory can predict quantitatively the magnetic properties of transition metal complexes.
(III) Valence bond theory cannot distinguish ligands as weak and strong field ones.

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Chemistry>Inorganic Chemistry>Coordination Compounds>VBT for Bonding in Coordination Compounds

The magnetic moment of an octahedral homoleptic

Mn (II)

complex is

5 .9 B . M .

. The suitable ligand for this complex is:

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Chemistry>Inorganic Chemistry>Coordination Compounds>VBT for Bonding in Coordination Compounds

The pair in which both the species have the same magnetic moment (spin only) is:

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Chemistry>Inorganic Chemistry>Coordination Compounds>VBT for Bonding in Coordination Compounds

An octahedral complex of Co³⁺ is diamagnetic. The hybridisation involved in the formation of the complex is :

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Chemistry>Inorganic Chemistry>Coordination Compounds>VBT for Bonding in Coordination Compounds

The one that can exhibit highest paramagnetic behaviour among the following is :

gly =

glycinato;

bpy = 2, 2

-

bipyridine

HARD

Chemistry>Inorganic Chemistry>Coordination Compounds>VBT for Bonding in Coordination Compounds

Choose the complex, which is paramagnetic

(i) ${[Fe {(H_{2} O)}_{6}]}^{2 +}$

(ii) $K_{3} [Cr {(CN)}_{6}]$

(iii) $K_{3} [Fe {(CN)}_{6}]$

(iv) $K_{2} [Ni {(CN)}_{4}]$

HARD

Chemistry>Inorganic Chemistry>Coordination Compounds>VBT for Bonding in Coordination Compounds

Choose the correct statement(s) among the following:

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Chemistry>Inorganic Chemistry>Coordination Compounds>VBT for Bonding in Coordination Compounds

Consider the following complex ions, P, Q and R.

$P = {[{FeF}_{6}]}^{3 -}, Q = {[V {(H_{2} O)}_{6}]}^{2 +}, R = {[Fe {(H_{2} O)}_{6}]}^{2 +}$

The correct order of the complex ions, according to their spin-only magnetic moment values (in B.M.) is

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Chemistry>Inorganic Chemistry>Coordination Compounds>VBT for Bonding in Coordination Compounds

Which of these statements about

{[C o {(C N)}_{6}]}^{3 -}

is true?

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Chemistry>Inorganic Chemistry>Coordination Compounds>VBT for Bonding in Coordination Compounds

Among

[N i {(C O)}_{4}], {[N i C l_{4}]}^{2 -}, [C o {(N H_{3})}_{4} C l_{2}] C l, N a_{3} [C o F_{6}], N a_{2} O_{2}

and

C s O_{2}

, the total number of paramagnetic compounds is

The observed magnetic moment of the complex [Mn(NCS)6)]x- is 6.06 BM. The numerical value of x is

Important Questions on Coordination Compounds

Learn and Prepare for any exam you want !

The observed magnetic moment of the complex $[Mn (NCS)_{6})]^{x -}$ is $6.06 BM$ . The numerical value of $x$ is