The $\mathrm{pH}$ of the solution containing $50 \mathrm{mL}$ each of $0.10 \mathrm{M}$ sodium acetate and $0.01 \mathrm{M}$ acetic acid is
[Given ${\mathrm{pK}}_{\mathrm{a}}$ of ${\mathrm{CH}}_3\mathrm{COOH}=4.57$]

$3{{\mathrm{O}}_2}_{\left(\mathrm{g}\right)}\rightleftharpoons 2{{\mathrm{O}}_3}_{\left(\mathrm{g}\right)}$,

for the above reaction at $298 \mathrm{K},{ \mathrm{K}}_{\mathrm{c}}$ is found to be $3.0\times {10}^{-59}$. If the concentration of ${\mathrm{O}}_2$ at equilibrium is $0.040 \mathrm{M}$, then concentration of ${\mathrm{O}}_3$ is: