EASY
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The process of boiling a liquid above its boiling point is called .

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Important Questions on Calorimetry and Change of State

EASY

Answer the following questions based on the P–T phase diagram of CO2

CO2 is heated to a temperature 70 oC and compressed isothermally. What changes in its properties do you expect to observe?

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The best method for the separation of naphthalene and benzoic acid from their mixture is
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The temperature at which the vapour pressure of a liquid equals the external pressure is called
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The following questions based on the P-T phase diagram of carbon dioxide:

Is CO2 solid, liquid or gas at (a) -70 oC under 1 atm, (b) -60 oC under 10 atm, (c) 15 oC under 56 atm?

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EASY

Answer the following questions based on the P–T phase diagram of CO2

What happens when CO2 at 4 atm pressure is cooled from room temperature at constant pressure?

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MEDIUM

Answer the following questions based on the P–T phase diagram of CO2:
CO2 at 1 atm pressure and temperature -60 oC is compressed isothermally. Does it go through a liquid phase?
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EASY

Answer the following questions based on the P–T phase diagram of CO2

Describe qualitatively the changes in a given mass of solid CO2 at 10 atm pressure and 65 oC temperature as it is heated up to room temperature at constant pressure.
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EASY
Using the following information determine the boiling point of a mixture contains 1560 g benzene and 1125 g chlorobenzene, when the external pressure is 1000 torr. Assume the solution is ideal.
Given, Molar mass of benzene = 78

Molar mass of chlorobenzene = 112.5
 
Temperature
(0oC)
Vapour pressure of benzene
(torr)
Vapour pressure of chlorobenznee (torr)
      80              750               120
      90             1000               200
     100             1350               300
     110             1800               400
     120             2200               540
EASY
The boiling point of C6H6, CH3OH, C6H5NH2 and C6H5NO2 are 80°C, 65°C, 184°C and 212°C, respectively. Which one will show the highest vapour pressure at room temperature?
MEDIUM

Assertion (A): The boiling point of water decreases as the altitude increases. 

Reason (R): The atmospheric pressure increases with altitude.

MEDIUM

The triple-point of water is a standard fixed point in modern thermometry. Why? What is wrong in taking the melting point of ice and the boiling point of water as standard fixed points (as was originally done in the Celsius scale) ?

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The following questions based on the P-T phase diagram of carbon dioxide:

What are the critical temperature and pressure for CO2? What is their significance?
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MEDIUM

The following questions based on the P-T phase diagram of carbon dioxide:
At what temperature and pressure can the solid, liquid and vapour phases of CO2 co-exist in equilibrium?
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EASY

The pair of boiling point and compound are given as,

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Which will show lowest vapour pressure at room temperature?

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In the phase diagram shown, the point Q corresponds to the triple point of water. The regions I, II, and III respectively corresponds to phases:
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MEDIUM
Normal boiling point TN is defined as the temperature when the vapour pressure of a liquid becomes equal to 1 atm and the standard boiling point TS is defined as the temperature at which the vapour pressure of a liquid becomes equal to 1 bar. Which one is not correct with regard to water?