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The reduction of which of the following compound would yield secondary amine?

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Important Questions on Organic Compounds Containing Nitrogen

EASY

Chemistry>Organic Chemistry>Organic Compounds Containing Nitrogen>Cyanides and Isocyanides

The most appropriate reagent for conversion of

C_{2} H_{5} CN

into

{CH}_{3} {CH}_{2} {CH}_{2} {NH}_{2}

is :

EASY

Chemistry>Organic Chemistry>Organic Compounds Containing Nitrogen>Cyanides and Isocyanides

Ethylamine

(C_{2} H_{5} N H_{2})

can be obtained from N-ethylphthalimide on treatment with:

HARD

Chemistry>Organic Chemistry>Organic Compounds Containing Nitrogen>Cyanides and Isocyanides

The best reagent for converting,

2 -

phenylpropanamide into

1 -

phenylethanamine is _____.

HARD

Chemistry>Organic Chemistry>Organic Compounds Containing Nitrogen>Cyanides and Isocyanides

In the reaction,

${CH}_{3} \cdot {CH}_{2} \cdot Cl \overset{KCN}{⟶} (A) \overset{{LiAlH}_{4}}{⟶} (P)$ end product $(P)$ is

EASY

Chemistry>Organic Chemistry>Organic Compounds Containing Nitrogen>Cyanides and Isocyanides

Which of the following statements is incorrect in case of Hofmann bromamide degradation?

HARD

Chemistry>Organic Chemistry>Organic Compounds Containing Nitrogen>Cyanides and Isocyanides

Starting from propanoic acid, the following reactions were carried out
Propanoic acid $\overset{{SOCl}_{2}}{⟶} X \overset{{NH}_{3}}{⟶} Y ⟶ Z_{2} + KOH \to Z$

What is the compound $Z$ ?

EASY

Chemistry>Organic Chemistry>Organic Compounds Containing Nitrogen>Cyanides and Isocyanides

Identify the amine formed when ethyltrimethyl ammonium iodide is treated with silver hydroxide and further heated strongly

MEDIUM

Chemistry>Organic Chemistry>Organic Compounds Containing Nitrogen>Cyanides and Isocyanides

When alkyl halide is boiled with large excess of alcoholic ammonia it forms

EASY

Chemistry>Organic Chemistry>Organic Compounds Containing Nitrogen>Cyanides and Isocyanides

Which of the following reaction is appropriate for converting acetamide to methanamine?

MEDIUM

Chemistry>Organic Chemistry>Organic Compounds Containing Nitrogen>Cyanides and Isocyanides

In the Hoffmann bromamide degradation reaction, the number of moles of

NaOH

and

B r_{2}

used per mole of amine produced are:

EASY

Chemistry>Organic Chemistry>Organic Compounds Containing Nitrogen>Cyanides and Isocyanides

Which one of the following compounds undergoes Hoffmann degradation reaction?

HARD

Chemistry>Organic Chemistry>Organic Compounds Containing Nitrogen>Cyanides and Isocyanides

An organic compound

A

on reduction gives a compound

B

B

on treatment with

{CHCl}_{3}

and alcoholic

KOH

gives

C

C

on catalytic reduction gives

N -

methylaniline. The compound

A

MEDIUM

Chemistry>Organic Chemistry>Organic Compounds Containing Nitrogen>Cyanides and Isocyanides

What are $P$ and $Q$ in the following reactions?

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EASY

Chemistry>Organic Chemistry>Organic Compounds Containing Nitrogen>Cyanides and Isocyanides

Which of the following compounds can be prepared in good yield by Gabriel phthalimide synthesis ?

EASY

Chemistry>Organic Chemistry>Organic Compounds Containing Nitrogen>Cyanides and Isocyanides

Identify $' A'$ in the following reaction $R - {NO}_{2} \to_{neutral medium}^{Zn / {NH}_{4} Cl} A + H_{2} O$

HARD

Chemistry>Organic Chemistry>Organic Compounds Containing Nitrogen>Cyanides and Isocyanides

What are

X, Y

and

Z

in the following reaction sequence?

Phthalamide \overset{Strongheating}{⟶} X ⟶ KOH / C_{2} H_{5} OH, Y ⟶ RX, Z

HARD

Chemistry>Organic Chemistry>Organic Compounds Containing Nitrogen>Cyanides and Isocyanides

Heating cyclohexene with

{KMnO}_{4} - H_{2} {SO}_{4}

gives

MEDIUM

Chemistry>Organic Chemistry>Organic Compounds Containing Nitrogen>Cyanides and Isocyanides

Which of the following amines can be prepared by Gabriel phthalimide reaction?

MEDIUM

Chemistry>Organic Chemistry>Organic Compounds Containing Nitrogen>Cyanides and Isocyanides

An aromatic compound

' A'

having molecular formula

C_{7} H_{6} O_{2}

, on treating with aqueous ammonia and heating forms compound

' B'

. The compound

' B'

on reaction with molecular bromine and potassium hydroxide provides compound

' C'

having molecular formula

C_{6} H_{7} N

. The structure of

' A'

is:

EASY

Chemistry>Organic Chemistry>Organic Compounds Containing Nitrogen>Cyanides and Isocyanides

On heating an aliphatic primary amine with chloroform and alcoholic potassium hydroxide, the organic compound formed is an:

The reduction of which of the following compound would yield secondary amine?

Important Questions on Organic Compounds Containing Nitrogen

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