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The solutions of two compounds listed in Column-I when taken in molecular proportions give coordination compounds on evaporation. Match these compounds with their relative properties which is/are listed in Column-II.

Column-I Column-II

A) $Fe {(C N)}_{2} + 4 KCN$ p) Coordination number of central metal ion in six

B) $CuS O_{4} + 4 N H_{3}$ q) Coordination number of central metal ion is four

C) $3 N a F + A l F_{3}$ r) Coordination number of central metal ion is two

D) $A g C N + KCN$ s) Oxidation state of central metal ion is +2

t) Overall charge on complex ion is +2

	Column-I		Column-II
A)	$Fe {(C N)}_{2} + 4 KCN$	p)	Coordination number of central metal ion in six
B)	$CuS O_{4} + 4 N H_{3}$	q)	Coordination number of central metal ion is four
C)	$3 N a F + A l F_{3}$	r)	Coordination number of central metal ion is two
D)	$A g C N + KCN$	s)	Oxidation state of central metal ion is +2
		t)	Overall charge on complex ion is +2

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Important Questions on Coordination Compounds

EASY

Chemistry>Inorganic Chemistry>Coordination Compounds>Werner's Theory of Coordination Compounds

Primary valency of

Co

[Co {(en)}_{2} {Cl}_{2}] Cl

EASY

Chemistry>Inorganic Chemistry>Coordination Compounds>Werner's Theory of Coordination Compounds

Which of the following types of valences, according to Werner's theory, is also called as primary valence ?

MEDIUM

Chemistry>Inorganic Chemistry>Coordination Compounds>Werner's Theory of Coordination Compounds

The conductivity measurement of a coordination compound of cobalt (III) shows that it dissociates into 3 ions in solution. The compound is

EASY

Chemistry>Inorganic Chemistry>Coordination Compounds>Werner's Theory of Coordination Compounds

The secondary valency and the number of hydrogen bonded water molecule(s) in ${CuSO}_{4} \cdot 5 H_{2} O$ , respectively, are:

EASY

Chemistry>Inorganic Chemistry>Coordination Compounds>Werner's Theory of Coordination Compounds

The correct order of the stoichiometries of

AgCl

formed when

{AgNO}_{3}

is treated in excess with the complexes:

{CoCl}_{3} . 6 {NH}_{3}, {CoCl}_{3} . 5 {NH}_{3}, {CoCl}_{3} . 4 {NH}_{3}

, respectively, is:

EASY

Chemistry>Inorganic Chemistry>Coordination Compounds>Werner's Theory of Coordination Compounds

The number of moles of ions formed on complete ionisation of

1

mole of

[Co {({NH}_{3})}_{3} {Cl}_{3}]

MEDIUM

Chemistry>Inorganic Chemistry>Coordination Compounds>Werner's Theory of Coordination Compounds

A d-block metal

M

forms two complexes with the formulae

{MCl}_{4} . 2 HCl

and

{MCl}_{2} . 2 {NH}_{3}

. When excess of

A g N O_{3}

solution is added to

1

mole of each complex,

A g C l

precipitate is not formed. The secondary valency of metal

M

in the complexes is respectively

EASY

Chemistry>Inorganic Chemistry>Coordination Compounds>Werner's Theory of Coordination Compounds

Which of the following co-ordinate complexes is an exception to EAN rule?

(Given At. Number Pt = 78, Fe = 26, Zn = 30, Cu = 29)

MEDIUM

Chemistry>Inorganic Chemistry>Coordination Compounds>Werner's Theory of Coordination Compounds

Which one of the following complexes will consume more equivalents of aqueous solution of

{AgNO}_{3}

MEDIUM

Chemistry>Inorganic Chemistry>Coordination Compounds>Werner's Theory of Coordination Compounds

According to Werner’s theory the geometry of the complex is determined by

MEDIUM

Chemistry>Inorganic Chemistry>Coordination Compounds>Werner's Theory of Coordination Compounds

Cobalt (III) chloride forms several octahedral complexes with ammonia. Which of the following will not give test for chloride ions with silver nitrate at

25^{o} C

MEDIUM

Chemistry>Inorganic Chemistry>Coordination Compounds>Werner's Theory of Coordination Compounds

On treatment of

100 mL

0.1 M

solution of

{CoCl}_{3} . 6 H_{2} O

with excess

{AgNO}_{3}; 1 .2 \times 10^{22}

ions are precipitated. The complex is:

EASY

Chemistry>Inorganic Chemistry>Coordination Compounds>Werner's Theory of Coordination Compounds

Which of the following pairs of complexes whose aqueous solutions gives pale yellow and white precipitates respectively with

0.1 {MAgNO}_{3} ?

EASY

Chemistry>Inorganic Chemistry>Coordination Compounds>Werner's Theory of Coordination Compounds

The number of cations produced by Mohr's salt in solution is

MEDIUM

Chemistry>Inorganic Chemistry>Coordination Compounds>Werner's Theory of Coordination Compounds

The correct order of electrical conductivity of the given complexes is

MEDIUM

Chemistry>Inorganic Chemistry>Coordination Compounds>Werner's Theory of Coordination Compounds

What is effective atomic number of

Fe

{[Fe {(CN)}_{6}]}^{4 -}

(At. no. of

Fe = 26

)

MEDIUM

Chemistry>Inorganic Chemistry>Coordination Compounds>Werner's Theory of Coordination Compounds

The volume $(i n m L)$ of $0.125 M {A g N O}_{3}$ required to quantitatively precipitate chloride ions in $0.3 g$ of $[C o {(N H_{3})}_{6}] C l_{3}$ is __________.
${}^{M}{[C o {(N H_{3})}_{6}]} C l_{3} = 267.46 g / m o l$
${}^{M}{A g N O}_{3} = 169.87 g / m o l$

Report the nearest integer as the answer.

EASY

Chemistry>Inorganic Chemistry>Coordination Compounds>Werner's Theory of Coordination Compounds

Addition of excess of ${AgNO}_{3}$ to an aqueous solution of $1$ mole of ${PdCl}_{2} \cdot 4 {NH}_{3}$ gives $2$ moles of $AgCl$ . The conductivity of this solution corresponds to:

EASY

Chemistry>Inorganic Chemistry>Coordination Compounds>Werner's Theory of Coordination Compounds

The number of ions produced in water by dissolution of the complex having the empirical formula,

{CoCl}_{3} 4 {NH}_{3},

EASY

Chemistry>Inorganic Chemistry>Coordination Compounds>Werner's Theory of Coordination Compounds

2.33

g of compound

X

(empirical formula

{CoH}_{12} N_{4} {Cl}_{3}

) upon treatment with excess

{AgNO}_{3}

solution produces

1 .435 g

of white precipitate. The primary and secondary valencies of cobalt in compound

X,

respectively, are

[Given: Atomic mass:

C o = 59, C l = 35.5, A g = 108]

Important Questions on Coordination Compounds

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