EASY
AS and A Level
IMPORTANT
Earn 100

The table shows the enthalpy changes needed to calculate the lattice energy of potassium oxide, K2O.

Type of enthalpy change Value of enthalpy change/kJ mol-1
first ionisation energy of potassium +418
first electron affinity of oxygen -141
second electron affinity of oxygen +798
enthalpy change of formation of K2O -361
enthalpy change of atomisation of potassium +89
enthalpy change of atomisation of oxygen +249

Use the data in the table above to calculate the lattice energy of potassium oxide.

Important Questions on Lattice Energy

MEDIUM
AS and A Level
IMPORTANT
Describe how, and explain why, the lattice energy of sodium oxide differs from that of potassium sulfide, K2S.
MEDIUM
AS and A Level
IMPORTANT

The table shows the enthalpy changes needed to calculate the lattice energy of potassium oxide, K2O.

Type of enthalpy change Value of enthalpy change/kJ mol-1
first ionisation energy of potassium +418
first electron affinity of oxygen -141
second electron affinity of oxygen +798
enthalpy change of formation of K2O -361
enthalpy change of atomisation of potassium +89
enthalpy change of atomisation of oxygen +249

Explain why the second electron affinity of oxygen has a positive value. 

MEDIUM
AS and A Level
IMPORTANT

Draw and label a Born-Haber cycle to calculate the lattice energy of sodium chloride.

MEDIUM
AS and A Level
IMPORTANT

Explain why the lattice energy of sodium chloride has a value that is lower than the lattice energy of lithium chloride.

MEDIUM
AS and A Level
IMPORTANT

Draw an energy cycle to show the dissolving of magnesium iodide in water.

EASY
AS and A Level
IMPORTANT

The table shows the values for all but one of the enthalpy changes relevant to this cycle.

Enthalpy change Value/kJ mol-1
lattice energy -2327
enthalpy change of hydration of Mg2+ ion -1920
enthalpy change of hydration of I- ion -314

Define enthalpy change of hydration.