HARD
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The theory of electrolytic dissociation suggests that:

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Important Questions on Electrochemistry

HARD
The equivalent conductance of NaCl at concentration C and at infinite dilution are λ C and λ , respectively. The correct relationship between λ C and λ is given as :
(where the constant B is positive)
EASY

Following figure shows dependence of molar conductance of two electrolytes on concentration. Λm0 is the limiting molar conductivity.

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The number of Incorrect statement(s) from the following is _____

(A) Λm0 for electrolyte A is obtained by extrapolation
(B) For electrolyte B,   Λm Vs c  graph is a straight line with intercept equal to Λm0
(C) At infinite dilution, the value of degree of dissociation approach zero for electrolyte B.
(D) Λm for any electrolyte A or B can be calculated using λ° for individual ions.

MEDIUM

Calculate the degree of dissociation () of acetic acid, if its molar conductivity (Ʌm) is 39.05 S cm2 mol-1

Given: λ°(H+)=349.6 S cm2 mol-1 and λ°(CH3COO-)=40.9 S cm2 mol-1.

HARD
Choose the correct representation of conductometric titration of benzoic acid vs sodium hydroxide.
EASY
Aqueous solution of which of the following compounds is the best conductor of electric current?
MEDIUM
The equivalent conductance of NaCl at concentration C and at infinite dilution are λC and λ respectively. The correct relationship between λC and λ is given as
HARD
Equivalent conductance of 1M CH3COOH is 10 ohm-1 cm2 equiv-1 and that at infinite dilution is 200 ohm-1 cm2, equiv-1. Hence % ionisation of CH3COOH is :
EASY
Aqueous solution of which of the following compounds is the best conductor of electric current?
EASY
Why methyl chloride does not form precipitates with AgNO3 though it contains chlorine ?
HARD

Given,

λ of 0.01 M MgCl2 is 220 S cm2 mol-1

λ° of MgCl2 is 240 S cm2 mol-1

λ° of Mg2+ is 100 S cm2 mol-1

All above measurements are done in an electrolytic cell. Assuming MgCl2 to be a strong electrolyte which of the following is/are incorrect?

EASY
Capacity of solvent to neutralise charge on ionic compound is called :-
EASY
For strong electrolytes the plot of molar conductance vsC is
EASY
Molten sodium chloride conducts electricity due to the presence of
MEDIUM

Represent the union of two sets by Venn diagram for each of the following.

X={x | x is a prime number between 80 and 100}

Y={y | y is an odd number between 90 and 100}

MEDIUM

Write down the changes that will be seen, explain the reason behind when dilute H2SO4 was taken in an electrolytic cell and electric current was passed through it.

MEDIUM

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Above plot represents the variation of molar conductivity against C (where, C= molar concentration of the electrolyte). Select the incorrect options among the following.

EASY
The pH of 0.005 M acid solution. What is the percentage ionization of the acid?