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Thermodynamic equilibrium is completely defined by the specifications of-

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Important Questions on Heat and Thermodynamics

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Pressure versus temperature graph of an ideal gas at constant volume V is shown by the straight-line A. Now mass of the gas is doubled and the volume is halved then the corresponding pressure versus temperature graph will be shown by the line

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Consider the following thermodynamical variables
(i) Pressure
(ii) Internal Energy
(iii) Volume
(iv) Temperature

Out of these, the intensive variable(s) is (are)

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Three different processes that can occur in an ideal monoatomic gas are shown in the P vs V diagram. The paths are labelled as AB,AC and AD. The change in internal energies during these process are taken as EAB,EAC and EAD and the work done as WAB,WAC and WAD. The correct relation between these parameters are:

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HARD
A one mole of ideal gas goes through a process in which pressure P varies with volume V as P=3-gVV02, where V0 is a constant. The maximum attainable temperature by the ideal gas during this process is (All quantities are in SI units and R is gas constant)
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A closed tank has two compartments A and B, both filled with oxygen (assumed to be ideal gas). The partition separating the two compartments is fixed and is a perfect heat insulator (Figure1). If the old partition is replaced by a new partition which can slide and conduct heat but does not allow the gas to leak across (Figure 2), the volume (in m3) of the compartment A after the system attains equilibrium is 20x m3. Write the value of x.

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A system goes from A to B via two processes I and II shown in the figure. If ΔU1 and ΔU2 are the changes in internal energies in the processes I and Il respectively

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n moles of an ideal gas undergoes a process AB as shown in the figure. The maximum temperature of the gas during the process will be:
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An ideal monoatomic gas is confined in a cylinder by a spring loaded piston of cross section 8 . 0 × 1 0 - 3 m 2 . Initially the gas is at 300K and occupies a volume of 2 . 4 × 1 0 - 3 m 3  and the spring is in its relaxed state as shown in figure. The gas is heated by a small heater until the piston moves out slowly by 0.1 m. The force constant of the spring is 8000 N/m and the atmospheric pressure is 1 . 0 × 1 0 5 N / m 2 .  The cylinder and the piston are thermally insulated. The piston and the spring are massless and there is no friction between the piston and the cylinder. The final temperature of the gas will be :
(Neglect the heat loss through the lead wires of the heater. The heat capacity of the heater coil is also negligible)


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Diagram shows a horizontal cylindrical container of length 30 cm, which is partitioned by a tight-fitting separator. The separator is diathermic but conducts heat very slowly. Initially the separator is in the state shown in the diagram. The temperature of left part of cylinder is 100 K and that on right part is 400 K. Initially the separator is in equilibrium. As heat is conducted from right to left part, separator displaces to the right. Find the displacement of separator(in cm) after a long time when gases on the two parts of cylinder are in thermal equilibrium.

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There are four objects A, B, C and D. It is observed that A and B are in thermal equilibrium and C and D are also in thermal equilibrium. However, A and C are not in thermal equilibrium. We can conclude that
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An ideal gas can be expanded from an initial state to a certain volume through two different processes i PV2=constant and ii P=KV2 where K is a positive constant. Then
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Explain why

(a) Two bodies at different temperatures T1 and T2 if brought in thermal contact do
not necessarily settle to the mean temperature (T1 + T2 )/2.

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In the arrangement shown in figure. Gas is thermally insulated. An ideal gas is filled in the cylinder having pressure P0 (> atmospheric pressure Pa). Spring of force constant k is initially unstretched. Piston of mass m and area S is frictionless. In equilibrium piston rises up a distance x0, then
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The thermo emf E (in volts) of a certain thermocouple is found to vary with Q (in C) according to equation E=20Q-Q220,where Q is temperature of the hot function, the cold function being kept at 0oC . Then, the neutral temperature of the thermocouple is
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One mole of an ideal gas at pressure P0 and temperature T0 is expanded isothermally to twice its volume and then compressed at constant pressure to V02 and the gas is brought back to original state by a process in which PV(pressure is directly proportional to volume). The correct temperature of the process is
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Two rigid boxes containing different ideal gases are placed on table. Box A contains one mole of nitrogen at temperature T0 , while box B contains 1 mole of helium at temperature 73T0. The boxes are then put into thermal contact with each other and heat flows between them until the gases reach a common final temperature (ignore the heat capacity of boxes) then the final temperature of gases, Tf in terms of T0 is
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P-T diagram is shown in the diagram. Choose the corresponding V-T diagram.

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Represent the union of two sets by Venn diagram for each of the following.

X={x | x is a prime number between 80 and 100}

Y={y | y is an odd number between 90 and 100}

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Is it possible for two bodies to be in thermal equilibrium if they are not in contact?
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There are four objects A, B, C and D. It is observed that A and B are in thermal equilibrium and C and D are also in thermal equilibrium. However, A and C are not in thermal equilibrium. We can conclude that