EASY
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Two vessels X and Y contain aqueous solutions of a weak acid HA  and its salt NaA, respectively. The following two equilibria HA+H2OH3O++A-and A-+H2O HA+OH-, exist in vessels X and Y, respectively. At equilibrium (at a given temperature T), the concentrations of HA,H3O+and A-in vessel X are C1,C2 and C3, respectively, while that of A-,HA and OH-in vessel Y, are C4,C5 and C6, respectively. Let the quantity C2·C3·C5·C6/C1·C4 be denoted by Q. The correct plot (lnQ vs 1 / T) is

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Important Questions on Equilibrium

MEDIUM
The degree of dissociation of 0.1M acid HA is 5%. The value of Kc of HA is
EASY
The acid dissociation constants of methanoic acid, monochloroethanoic acid and ethanoic acid are K1, K2 and K3 respectively. If K2>K1>K3, then
EASY
The pH of 0.1M solution of acetic acid will be [degree of dissociation of acetic acid is 0.0132]
MEDIUM

Given below are two statements: one is labelled as Assertion A and the other is labelled as Reason R.

Assertion A :Phenolphthalein is a pH dependent indicator, remains colourless in acidic solution and gives pink colour in basic medium

Reason R : Phenolphthalein is a weak acid. It doesn't dissociate in basic medium.

In the light of the above statements, choose the most appropriate answer from the options given below

HARD
The initial rate of hydrolysis of methyl acetate1M by a weak acid (HA, 1M) is 1/100th of that by a strong acid HX, 1M, at 25°C. The Ka of HA is
EASY
Match the following
List-1
Acid
List-2
Ka(ionization constant)
A) HCN I) 6.8×10-4
B) H2C2O4 II) 8.9×10-8
C) H2S III) 4.9×10-10
D) Niacin IV) 5.6×10-2
    V) 1.5×10-5

The correct match is
MEDIUM
CH3COOH is 1% ionised in its aqueous solution of 0.1M strength. Its pOH will be
MEDIUM

0.01 moles of a weak acid HA Ka=2.0×10-6 is dissolved in 1.0 L of 0.1M HCl solution. The degree of dissociation of HA is __________ ×10-5 (Round off to the Nearest Integer). [Neglect volume change on adding HA and assume degree of dissociation <<1]

MEDIUM
At T(K), if the ionization constants of HCOOH and HCN are 2.0×10-4 and 5.0×10-9, respectively, the ionization constants of the corresponding conjugate bases, respectively, are
HARD
Sulphurous acid H2SO3 has Ka1=1.7×10-2 and Ka2=6.4×10-8. The pH of 0.588 M H2SO3 is____________ (Round off to the Nearest Integer).
HARD
Ka for butyric acid C3H7COOH is 2×10-5. ThepH of 0.2M solution of butyric acid is____×10-1. (Nearest integer) [Given log2=0.30]
MEDIUM
The pH of an aqueous solution of 10-8MHCl is
EASY

The degree of dissociation of 0.1mol L-1acetic acid in water is

( K of acetic acid is 10-5

HARD
Acetylsalicylic acid has pKa value 3.5. The pH of gastric juice in human stomach is 2-3 and the pH in the small intestine is approximately 7.4. Then acetylsalicylic acid will be
MEDIUM
The degree of dissociation of 0.1 N CH3COOH is (given Ka=1×10-5) approximately _________
EASY
Ka values for acids H2SO3,HNO2,CH3COOH and HCN are respectively 1.3×10-2,4×10-4, 1.8×10-5  and 4×10-10, which of the above acids produces stronger conjugate base in aqueous solution?
EASY
Ostwald's dilution law is applicable only for
MEDIUM
0.004 M Na2SO4 is isotonic with 0.01 M glucose solution. The degree of dissociation of Na2SO4 is
EASY
Assuming that Ba(OH)2 is completely ionised in aqueous solution under the given conditions the concentration of H3O+ ions in 0.005M
aqueous solution of Ba(OH)2 at 298 K is _________ ×10-12 mol L-1. (Nearest integer)
MEDIUM
An aqueous solution in which the H+ ion concentration is greater than 10-7 M is said to be