MEDIUM
Earn 100

What are electrophiles? Explain with examples.

Important Questions on Organic Chemistry-II

EASY
Reaction of a carbonyl compound with one of the following reagents involves nucleophilic addition followed by elimination of water. The reagent is:
MEDIUM

The major product of the following reaction is:Question Image

HARD
In the following reaction sequence, the amount of D (in g) formed from 10 moles of acetophenone is ____.

(Atomic weights in mol-1: H=1,C=12,N=14,O=16,Br=80.  The yield (%) corresponding to the product in each step is given in the parenthesis)

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EASY
An organic compound 'X' having molecular formula C5H10O yields phenyl hydrazone and gives negative response to the iodoform test and Tollen's test. It produces n-pentane on reduction. 'X' could be:
MEDIUM

In the following reactions, products A and B are:

Question Image

 

MEDIUM

The increasing order of the reactivity of the following with LiAlH4 is:

(A) Question Image

(B) Question Image

(C) Question Image

(D) Question Image

EASY
Aldehydes or ketones when treated with C6H5-NH-NH2, the product formed is
MEDIUM

The major product formed in the following reaction is:
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HARD
The test performed on compound x and their inferences are:
 
Test Inference
a 2, 4 - DNP test Coloured precipitate yellow
b Iodoform test Yellow precipitate
c Azo-dye test No dye formation

Compound x is:

MEDIUM
The major product B formed in the following reaction sequence is:

Question Image
MEDIUM

The major product 'X' formed in the following reaction is:

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EASY

In the reaction sequence

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The major product X and Y, respectively, are

HARD
In the reaction sequence

2CH3CHO OH- A  B ; the product B is:
MEDIUM
Formaldehyde on reaction with ammonia gives a compound A, which is on nitration yields cyclonite. The compound  A is
MEDIUM
The reaction of ethyl methyl ketone with Cl2 excess OH- gives the following major product
HARD
A compound of molecular formula C8H8O2 reacts with acetophenone to form a single cross-aldol product in the presence of base. The same compound on reaction with concentrated NaOH forms benzyl alcohol as one of the products. The structure of the compound is:
HARD

The major product obtained in the following reaction is:
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EASY
In the following reaction
Aldehyde+AlcoholHClAcetal
Aldehyde  Alcohol
HCHO t-BuOH
CH3CHO  MeOH
The best combination is:
EASY
The product formed by the reaction of an aldehyde with a primary amine is: