MEDIUM
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Important Questions on Chemical Bonding and Molecular Structure

EASY
The number and type of bonds in C22- ion in CaC2 are:
HARD
The value of nI for which the function f(x)=sinnxsin(xn) has 4π as its period is:
MEDIUM
A monoatomic gas of mass 4.0 u is kept in an insulated container. The container is moving with velocity 30 m s-1. If the container is suddenly stopped then a change in temperature of the gas (R=gas constant) is x3R. Value of x is,
EASY
The number of sigma σ and pi π bonds in pent- 2 -en- 4 -yne is:
EASY

Match the physical quantities with their correct SI units.

  List-I   List-II
(A) Planck's constant (I) kg m s-2
(B) Torque (II) kg-1 m3
(C) Weight (III) m2 kg s-1
(D) Specific volume (IV) kg m2 s-2

The correct match is

EASY
The correct thermodynamic conditions for the spontaneous reaction at all temperatures is:
EASY
2 kg of a monoatomic gas is at a pressure of 4×104 N m-2. The density of the gas is 8kg m-3. What is the order of energy of the gas due to its thermal motion?
EASY
Calculate the specific heat capacity Cv of a gaseous mixture consisting of v1 moles of a gas of adiabatic exponent γ 1  and v 2  moles of another gas of adiabatic exponent γ 2 .
EASY

Starting with the same initial conditions, an ideal gas expands from volumeV1 to V2 in three different ways. The work done by the gas is W1 if the process is purely isothermal,W2 if purely isobaric and purely adiabatic. Then
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EASY
If gas expands at constant temperature and pressure, then its
EASY
The percentage change in internal energy, when a gas is cooled from 927 °C to 27 °C, is
EASY
A cyclic process ABCD is shown in the following P-V diagram. Which of the following curves represents the same process?

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EASY
For the reaction (at 1240 K and 1 atm.)

CaCO3sCaOs+CO2(g)

H=176 kJ/mol; E will be
MEDIUM
The final volume of a system is equal to the initial volume in a certain process. Is the work done by the system necessarily zero? Is it necessarily nonzero?
EASY
In the figure, a certain mass of gas traces three paths 1, 2, 3 from state A to state B. If work done by the gas along three paths are W1, W2, W3 respectively, then
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MEDIUM
The outer surface of a cylinder containing a gas is rubbed vigorously by a polishing machine. The cylinder and its gas become warm. Is the energy transferred to the gas heat or work?
EASY
Among the following gases, the one which possesses the largest internal energy is
EASY
Which one of the following statements is true, in respect of the usual quantities represented by Q, U and W.
EASY

An ideal gas is taken around the cycle ABCA as shown in the pV diagram

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The total work done by the gas during the cycle is