MEDIUM
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What is the term used to describe the price at which the quantity demanded equals the quantity supplied?

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Important Questions on Equilibrium

HARD

A(g)2 B( g)+C(g)

For the given reaction, if the initial pressure is 450 mmHg and the pressure at time t is 720 mmHg at a constant temperatureT and constant volume V. The fraction of A(g) decomposed under these conditions is x×10-1. The value of x is (nearest integer)

HARD
4.0 moles of argon and 5.0 moles of PCl5 are introduced into an evacuated flask of 100 litre capacity at 610 K. The system is allowed to equilibrate. At equilibrium, the total pressure of mixture was found to be 6.0 atm. The Kp for the reaction is [Given : R=0.082 L atm K-1 mol-1 ]
EASY
Addition of sodium hydroxide solution to a weak acid (HA) results in a buffer of pH 6. If ionization constant of HA is 10-5, the ratio of salt to acid concentration in the buffer solution will be:
HARD

For a reaction at equilibrium

 AgBg+12Cg

 the relation between dissociation constant K, degree of dissociation α and equilibrium pressure p is given by :

MEDIUM
At 60°C, dinitrogen tetroxide is fifty percent dissociated. Find its standard free energy change at this temperature and one atmosphere. [ Given: log1.33=0.1239 ]
EASY
For NH4HSsNH3g+H2 Sg  the
observed pressure for the reaction mixture in equilibrium is 1.12 atm at 106°C. What is the value of Kp for the reaction?
EASY
Which one of the following pairs of solution is not an acidic buffer?
MEDIUM

For the reaction

H2g+CO2gCOg+H2Og, if the initial concentration of H2=CO2 = 1M and x moles/L of H2 is consumed at equilibrium, the correct expression of KP is.

HARD
For the reaction AgBg+Cg, A is 33% dissociated at a total pressure P. The correct relation between P and Kp is
MEDIUM
A sample of HI(g) is placed in a flask at a pressure of 0.2 atm. At equilibrium, partial pressure of HI(g) is 0.04 atm. What is Kp for the given equilibrium ? 2HI(g)H2( g)+I2(g)
HARD
A 20 litre container at 400 K contains CO2g at pressure 0.4 atm and an excess of SrO (neglect the volume of solid SrO ). The volume of the container is now decreased by moving the movable piston fitted in the container. The maximum volume of the container, when the pressure of CO2 attains its maximum value, will be:

Given that:SrCO3sSrOs+CO2g, Kp=1.6 atm
MEDIUM

Which of the following statements is correct?

MEDIUM
What do you understand by dynamic nature of chemical equilibrium? Give one experiment to prove that equilibrium is dynamic in nature.
EASY
List any four important characteristics of a chemical equilibrium.
EASY
What do you understand by chemical equilibrium? Explain with one suitable example.
MEDIUM

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Among the following points indicated on the graph, which one represents equilibrium?

EASY
Define 'homogeneous equilibria and heterogeneous equilibria'. Give three examples of each of them.
MEDIUM
For the synthesis of ammonia by the reaction N2+3H22NH3 in the Haber's process, the attainment of equilibrium is correctly predicted by the curve
MEDIUM
Based upon the following hypothetical equilibria at 273 K:

XCl2·6H2OsXCl2·2H2OS+4H2Ov ; Kp = 8.1 × 10-11 atm4

Y2HPO4·12H2OsY2HPO4·7H2Ov+5H2Og ; Kp = 3.2 × 10-9 atm5

Z2SO4·10H2OsZ2SO4s+10H2Ov ; Kp  = 1.0 × 10-30 atm10

Which is the most effective dehydrating agent at 273 K? (Aqueous tension at 273 K is 6.0 × 10-3 atm)