EASY
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What will be the value of ΔG for ice at 8oC temperature?

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Important Questions on Chemical Thermodynamics

EASY

At what temperature, a chemical reaction will have following values?

ΔG=4 kJ,ΔH=-60 kJ,ΔS=-160 J

MEDIUM

Consider the following reactions occurring in an automobile, C8H18(g)+252O2(g)8CO2(g)+9H2O(g)

The sign of ΔH, ΔS and ΔG respectively would be,

EASY
Which reaction either endothermic or exothermic characteristics has the greater chance of occuring spontaneously?
EASY
For a reaction, ΔH=9.08 kJ mol-1 and ΔS=35.7 J K-1 mol-1.

Which of the following statements is correct regarding the reaction?
EASY
In a reaction, ΔH and ΔS, both are more than zero. In which of the following cases would the reaction be spontaneous?
EASY
In conversion of limestone to lime,

CaCO3sCaOs+CO2(g)

the values of H° and S° are +179.1 KJ/mol ,160.2J/K respectively at 298 K and 1 bar. Assuming that  H° and S° do not change with temperature, temperature above which conversion of limestone to lime will be spontaneous is
MEDIUM
Assertion: Many endothermic reactions that are not spontaneous at room temperature become spontaneous at high temperature. Reason: Entropy of the system increases with increase in temperature.
EASY
In which of the following reactions, standard reaction entropy change (ΔSo) is positive and standard Gibb's energy change (ΔGo) decreases sharply with increasing temperature?
EASY
For a reaction ΔH=-9.08 kJ mol-1 and

ΔS=35.7 JK-1mol-1

Which of the following statements is correct for the reaction?
EASY
If a process is both endothermic and spontaneous , then :
EASY
Considering entropy S as a thermodynamic parameter, the criterion for the spontaneity of any process is
EASY
Which of the following processes is a non-spontaneous process?
HARD
In an irreversible process taking place at constant T and p and in which only pressure-volume work is being done, the change in Gibbs free energy (dG) and change in entropy (dS), satisfy the criteria.
EASY
In the process of ice melting at -15°C,
HARD
In an irreversible process taking place at constant T and P and in which only pressure volume work is being done, the change in Gibb's free energy G and change in entropy S , satisfy the criteria
MEDIUM
A change that can occur on its own is called
MEDIUM
The factor of ΔG values is important in metallurgy. The ΔG values for the following reactions at 800oC are given as:

S2g+2O2g2SO2g;  ΔG= -544 kJ

2Zns+S2g2ZnSs;  ΔG=-293 kJ

2Zns+O2g2ZnOs;  ΔG=-480 kJ

The ΔG for the reaction,

2ZnSg+3O2g2ZnOg+2SO2g ;  will be
MEDIUM
Identify the correct statement regarding a spontaneous process :