MEDIUM
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What will happen to the following equilibrium reaction if pressure is applied on it?

H2O(l)H2O(g)

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Important Questions on Equilibrium

EASY
Burning the coal is represented as C(s)+O2(g)CO2(g).
The rate of this reaction is increased by
MEDIUM

The value of Kc us 64 at 800 K for the reaction

N2g+3H2g2 NH3 g

The value of Kc for the following reaction is :

NH3 g12 N2 g+32 H2 (g)

MEDIUM
A sample of HI(g) is placed in a flask at a pressure of 0.2 atm. At equilibrium, partial pressure of HI(g) is 0.04 atm. What is Kp for the given equilibrium ? 2HI(g)H2( g)+I2(g)
MEDIUM
For the reaction:   2NO2g2NOg+O2g, 

Kc=1.8×10-6 at 184oCR=0.0831J/molK

When  Kp and Kc are compared at 184oC. It is found that
MEDIUM
The equilibrium constant for the reaction is P4s+502gP4010s
EASY
The pH of the blood is maintained by buffer system given by
HARD

The reaction

CaCO3sCaOs+CO2g

is in equilibrium in a closed vessel at 298 K. The partial pressure (in atm) of CO2g in the reaction vessel is closest to:

[Given: The change in Gibbs energies of formation at 298 K and 1 bar for

CaO(s)=-603.501 kJ mol-1

CO2g=-394.389 kJ mol-1

CaCO3s=-1128.79 kJ mol-1

Gas constant R=8.314 J K-1 mol-1]

EASY
The decay profiles of three radioactive species A, B and C are given below:

Question Image

These profiles imply that the decay constants kA, kB and kC follow the order
MEDIUM

Using the data provided, find the value of equilibrium constant for the following reaction at 298 K and 1 atm pressure. NO(g)+12O2( g)NO2( g)
ΔfH0NO(g)=90.4kJ.mol1

ΔfH0NO2(g)=32.48kJmol1

ΔSat 298K=70.8JK1mol1

antilog(0.50)=3162

MEDIUM
Which one of the following is NOT an example of heterogeneous equilibrium?
MEDIUM
Among the following, the correct statement about the chemical equilibrium is.
EASY
There are two statements, one labelled as Assertion (A) and the other as Reason (R). Examine both the statements carefully and mark the correct choice.
(A) At equilibrium, the mass of each of the reactants and products remains constant.
(R) At equilibrium, the rate of forward reaction is equal to the rate of backward reaction.
EASY
For the equilibrium AB, the variation of the rate of the forward (a) and reverse (b) reaction with time is given by:
MEDIUM
Calculate variation of EMF of a cell E, with temperature T, If G=H-TS and G=H+TdGdTp.
EASY
The enthalpy and entropy change for the reaction are 30 kJ mol-1 and 105 J K-1 mol-1, respectively. The temperature at which the reaction will be in equilibrium is

Br2 l+Cl2 g2BrCl g
HARD

Find the total pressure of cases over a mixture of X and Y, ​​​​​​​​when two solid compounds 'X' and 'Y' dissociates at a certain temperature is as follows:
X(s)A(g)+2B(g)Kp1=9×10-3atm3

Y(s)2B(g)+C(g) Kp2=4.5×10-3 atm3

EASY

A+BC+2D.....(i)

A+EC+F.(ii)

If K1 and K2 are equilibrium constants for the reactions (i) and (ii), respectively, then find out the equilibrium constant for the reaction E+2DB+F.

HARD
The dissociation equilibrium of a gas AB 2 can be represented as, 2AB2(g) 2AB(g)+B2(g). The degree of dissociation is x and is small as compared to 1 . The expression relating the degree of dissociation (x) with equilibrium constant K P and total pressure P is:
EASY
Nitric oxide reacts with Br2 and gives nitrosyl bromide as per the reaction given below.

                      2NOg + Br2g  2NOBrg

When 0.087 mole of NO and 0.0437 mole of Br2 are mixed in a closed container at a constant temperature, 0.0518 mole of NOBr is obtained at equilibrium. Calculate the equilibrium amount of NO and Br2.
EASY

In which direction does the reaction tend to shift to reach equilibrium given at a particular time, the analysis shows that composition of reaction mixture is 3.0 mol L-1 N2, 2.0 mol L-1 H2 and 0.5 mol L-1 NH3.

Equilibrium constant, Kc for the below reaction is

N 2 g + 3H 2 g 2NH 3 g at 500 K is 0.061