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JEE Main / Advanced
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When a liquid evaporates, the heat supplied to it is used partially to do work in overcoming the forces of cohesion between the molecules (the internal heat of vaporization) and partially to do work against the forces caused by external pressure (the external heat of vaporization). How to determine the external heat of vaporization from the graph representing the experimental isotherm of a real gas?

Important Questions on Molecular Physics and Thermodynamics

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JEE Main / Advanced
IMPORTANT
Gas cylinders and pipes intended for operation under high pressures are usually tested not by pumping air or a gas into them but by filling them with a liquid, water or oil, and raising the pressure up to the test value. This is done in accordance with safety regulations. What is the explanation for this?
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JEE Main / Advanced
IMPORTANT

To demonstrate the transition to the critical state, a liquid (usually ethyl ether) is placed inside a small sealed thick-walled glass tube. The tube is then sealed off (Figure) and slowly heated. It is found that in the process of heating the boundary between the liquid and the vapour above the liquid rises and the meniscus becomes flatter (Figure). It is extremely difficult to observe the transition through the critical temperature because of intense convective fluxes, but the result is seen because at this temperature the meniscus disappears completely (Figure). Upon slowly cooling the tube it is found that at the same temperature the entire volume becomes cloudy, so that light cannot pass through the tube (Figure). If the temperature is lowered still further, the volume becomes transparent and there appears a meniscus, which separates the two phases. Explain the reasons for the observed phenomena.

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JEE Main / Advanced
IMPORTANT
How does the temperature of a liquid change under adiabatic evaporation?
EASY
JEE Main / Advanced
IMPORTANT
The bending of the surface of a liquid creates excess pressure (known as the Laplace pressure). Because of this the pressure inside a soap bubble is somewhat higher than the atmospheric pressure. In a drop, too, there is excess pressure. Suppose we have a drop of liquid and a soap bubble of the same liquid and the same diameter. Where is the pressure greater: inside the drop or inside the bubble?
EASY
JEE Main / Advanced
IMPORTANT

Two soap bubbles of different diameters are blown out using a T-shaped pipe (see the figure). Will the diameters of the bubbles remain unchanged?

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MEDIUM
JEE Main / Advanced
IMPORTANT

Three drops of different diameters are in the atmosphere of the vapor of the liquid from which the drops are formed. The pressure of the vapor is such that the drop with the medium diameter (Figure) is in equilibrium with the vapor. Is this equilibrium stable? How will the drops of the smaller (Figure) and the larger (Figure) diameters behave?

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JEE Main / Advanced
IMPORTANT

Two drops are placed between two parallel glass plates, a drop of water (Figure a) and a drop of mercury (Figure b). What forces act on the plates in each case?

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JEE Main / Advanced
IMPORTANT

Inside two conical pipes there is a drop of water (Figure) and a drop of mercury (Figure). Where does each drop tend to move?

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