Which of the following compounds are not reduced by glucose?

${\mathrm{CH}}_2\mathrm{OH}(\mathrm{CHOH}{)}_4\mathrm{CHO}+\mathrm{HCN}\to \mathrm{X}$

Identify the compound $\mathrm{X}$ in the above reaction?

Which of the list shown below have the correct pair of the structure of alanine in $\mathrm{pH}$ ranges $2-4$ and $9-11$ is

I. ${\mathrm{H}}_3\stackrel{+}{\mathrm{N}}-\mathrm{CH}\left({\mathrm{CH}}_3\right){\mathrm{CO}}_2\mathrm{H}$

II. ${\mathrm{H}}_2\mathrm{N}-\mathrm{CH}\left({\mathrm{CH}}_3\right){\mathrm{CO}}_2^{-}$

III. ${\mathrm{H}}_3\stackrel{+}{\mathrm{N}}-\mathrm{CH}\left({\mathrm{CH}}_3\right){\mathrm{CO}}_2^{-}$

IV. ${\mathrm{H}}_2\mathrm{N}-\mathrm{CH}\left({\mathrm{CH}}_3\right){\mathrm{CO}}_2\mathrm{H}$