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Which of the following has maximum nucleophilicity?

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Important Questions on Organic Chemistry- Some Basic Principles and Techniques

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Consider thiol anion RSand alkoxy anionRS. Which of the following statement is correct?
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Compare the melting point (MP) and dipole moment (μ) of the above compounds:

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Which of the following does not contain any asymmetric carbon but can show enantiomerism:
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Which of the following represents the structure having cis arrangement around each double bond: