HARD
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Write balanced chemical equation for the action of dilute:

sulphuric acid on diethylamine

Important Questions on Amines

MEDIUM
The correct match between column-I and column-II is
 
Column-I (drug) Column-II (test)
(A) Chloroxylenol (P) Carbylamine test
(B) Norethindrone (Q) Sodium hydrogen carbonate test
(C) Sulphapyridine (R) Ferric chloride test
(D) Penicillin (S) Baeyer’s test
HARD

The major product of the following reaction is:

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MEDIUM
The following reaction

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Is known by the name:
EASY
Which of the following compounds will form significant amount of meta product during mono-nitration reaction?
HARD
The product(s) of the following reaction sequence is(are)

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MEDIUM
A compound with molecular mass 180 is acylated with CH3COCl to get a compound with molecular mass 390. The number of amino groups presents per molecule of the former compound is
HARD

Aniline reacts with mixed acid (conc. HNO3 and conc. H2SO4 ) at 288 K to give P (51 %), Q (47%) and R (2%) . The major product(s) of the following reaction sequence is (are)

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MEDIUM
Among the following compounds, the increasing order of their basic strength is:

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MEDIUM

The major product formed in the reaction given below will be :

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HARD

The major product obtained in the following reaction is:
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MEDIUM
The amine which reacts with p-toluene sulphonyl chloride to give a clear solution which on acidification gives insoluble compound is
HARD
The cyclobutyl methylamine with nitrous acid gives
EASY
The nitrosation of N,N-dimethylaniline takes place through the attack of electrophile:
EASY
A mixture containing the following four compounds is extracted with 1 M HCl. The compound that goes to aqueous layer is:
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HARD
The compound  X C7H9N reacts with benzenesulfonyl chloride to give  Y C13H13NO2S which is insoluble in alkali. The compound X is
EASY
Describe a method for the identification of primary, secondary and tertiary amines. Also, write chemical equations of the reactions involved.
MEDIUM

What will be the major product in the following mononitration reaction?

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EASY
Nitration of aniline in strong acidic medium also gives m-nitroaniline because:
MEDIUM
Identify the product 'C' in the following reaction.

Aniline CH3CO2OPyridine A Br2CH3COOH B H+ or OH- C