Kohlrausch's Law

IMPORTANT

Kohlrausch's Law: Overview

This topic covers concepts, such as, Kohlrausch's Law, Applications of Kohlrausch's Law, Ostwald's Dilution Law for Weak Electrolytes & Determination of Solubility of a Sparingly Soluble Salt etc.

Important Questions on Kohlrausch's Law

EASY
IMPORTANT

The law that states about independent migration of ions is:

HARD
IMPORTANT

Find the solubility product of a saturated solution of Ag 2 CrO 4   at 298 K in water if the emf of the cell  Ag Ag + Ag 2 CrO 4 Ag + 0 .1 M Ag s is 0.164 V at 298 K.

MEDIUM
IMPORTANT

Electrolyte KCl KNO3 HCl NaOAc NaCl
 S cm2 mol-1 149.9 145.0 426.2 91.0 126.5


Calculate  Λ o HOAC  at infinite dilution in   H 2 O at   25°C :

EASY
IMPORTANT

The molar conductance and the specific conductance of an electrolyte are related by the formula

EASY
IMPORTANT

The molar conductance of 0.01 M electrolyte is 124 ohm-1 cm2 mol-1 at 298 K. Calculate its specific conductance.

EASY
IMPORTANT

The specific conductance of 0.01 M of an electrolyte is 1.24×10-3 ohm-1 cm-1 at 298 K. Calculate the molar conductance.

EASY
IMPORTANT

Calculate the molar conductance of 0.02 M solution of an electrolyte which has a resistance of 310 ohm at 298 K. Cell constant is 0.68 cm-1.

MEDIUM
IMPORTANT

The equivalent conductivity of acetic acid at infinite dilution is 387 S cm2 eq-1. At the same temperature, for 0.001 M solution of acetic acid, it is 55 S cm2 eq-1. What is the degree of dissociation of 0.1 N acetic acid? Assume 1-α1

A : 1.5%B : 1.35%C : 2%

Enter your correct answer as A, B or C.

MEDIUM
IMPORTANT

Which statement is not correct for Kohlrausch law?

HARD
IMPORTANT

If the value of molar conductivities at infinite dilution for CH3COOHHCl and NaCl are 390.5, 425.4 and 126.4 S cm2mol-1 respectively at 298 K. Calculate the molar conductivity at infinite dilution of CH3COONa in S cm2mol-1. (Just mention the value, no requirement of units in the answer).

HARD
IMPORTANT

The maximum molar conductivities of X+3 and Y- ions are 200 and 100 S cm2 mol-1 respectively. The molar conductivity of XY3 at infinite dilution is :-

MEDIUM
IMPORTANT

Define limiting molar conductivity Λ°m.

MEDIUM
IMPORTANT

m NH4OH0 is equal to _____.

HARD
IMPORTANT

What is the molar conductivity of AgI at zero concentration if the 0 values of NaI, AgNO3 and NaNO3 are respectively 126.9 Ω-1cm2mol-1133.4 Ω-1cm2mol-1, 121.5 Ω-1cm2mol-1?

HARD
IMPORTANT

How is the molar conductivity of strong electrolytes at zero concentration determined by graphical method? Why is this method not useful for weak electrolytes?

HARD
IMPORTANT

The molar conductivities at zero concentrations of NH4Cl, NaOH and NaCl are respectively 149.7Ω-1cm2mol-1, 248.1Ω-1cm2mol-1 and 126.5Ω-1cm2mol-1. What is the molar conductivity of NH4OH at zero concentration?

MEDIUM
IMPORTANT

What will be the calculated value of standard electrode potential(E0) Cl-/AgCl/Ag at 298 K temperature, if solubility of silver chloride (AgCl) in 0.05 M BaCl2 is nearly 10-9 M (E0 Ag/Ag+=0.80 volts).

EASY
IMPORTANT

The  equivalent conductance of 1M CH3COOH is 10 ohm-1cm2eq-1 and at infinite dilution is 200 ohm-1cm2/eq. Calculate the value of degree of ionization  of  Ac-OH (CH3COOH).

HARD
IMPORTANT

Which of the following graph is/are correct for a weak acid (HA), where symbols have usual meaning?

HARD
IMPORTANT

The values of Λeq for NH4Cl, NaOH and NaCl are, respectively, 149.74, 248.1 and 126.4 ohm-1cm2eq-1 . The value of Λeq NH4OH inohm1cm2eq1 is