Equivalent Concept

IMPORTANT

Equivalent Concept: Overview

This topic covers concepts such as Normality, Law of Equivalence, Equivalence, Calculation of Number of Equivalence, Equivalent Weight, Valency Factor, Valency Factor of Chemical Compounds, Valency Factor for an Acid, Valency Factor for a Base, etc.

Important Questions on Equivalent Concept

EASY
IMPORTANT

What is the  [OH]  in the final solution prepared by mixing 20.0 mL of 0.050 M HCl with 30.0 mL of 0.10  M Ba(OH)2 ?

MEDIUM
IMPORTANT

The equivalent weight of   N a 2 S 2 O 3 .5 H 2 OandKBr O 3  In the following reactions would be:

  (i)2 S 2 O 3 2 + I 2 S 4 O 6 2 +2 I (ii)Br O 3 +6 H + +6 e B r +3 H 2 O

MEDIUM
IMPORTANT

The density of copper is  8.94 g ml1.  The number of coulombs needed to plate an area   10cm×10cm  to a thickness  102 cm using CuSO4 solution as electrolyte are:

MEDIUM
IMPORTANT

Vapour density of a metal chloride is 66. Its oxide contains 53% metal. The atomic weight of the metal is

MEDIUM
IMPORTANT

If 6×10-3 mole of K2Cr2O7 reacts completely with 9×10-3 mole of Xn+ to give XO3- and Cr3+, then, the value of n is

MEDIUM
IMPORTANT

The equivalent weight of an element is 4. Its chloride has a vapour density 59.25. Then the valency of the element is

EASY
IMPORTANT

Arsenic forms two oxides, one of which contains 65.2% and the other 75.7% of the element. Hence, equivalent masses of arsenic are in the ratio :

HARD
IMPORTANT

Carbon forms two oxides, namely carbon monoxide and carbon dioxide. The equivalent mass of which element remains constant? 

HARD
IMPORTANT

Volume V1 mL of 0.1M K2Cr2O7 is needed for complete oxidation of 0.678g N2H4 in acidic medium. The volume in mL of 0.3 M KMnO4 needed for same oxidation in the acidic medium will be

MEDIUM
IMPORTANT

In alkaline medium, KMnO4 reacts as follows (Atomic weights K=39.09, Mn=54.94, O=16.00)

2KMnO4+2KOH2K2MnO4 +H2O+[O]

Hence, its equivalent weight is

HARD
IMPORTANT

Equivalent weight of chlorine molecule in the equation is : 3Cl2+ 6NaOH 5NaCl+ NaClO3+3H2O

MEDIUM
IMPORTANT

An aqueous solution of 6.3 g of oxalic acid dihydrate is made up to 250 mL. The volume of 0.1 N NaOH required to completely neutralize 10 mL of this solution is

HARD
IMPORTANT

In the conversion of NH2OHN2O, the equivalent weight of NH2OH is

(M=molecular weight of NH2OH)

HARD
IMPORTANT

When HNO3 is converted to NH3, the equivalent weight of HNO3 will be

(M=molecular weight of HNO3)

HARD
IMPORTANT

The mass of oxalic acid crystals H2C2O4.2H2O required to prepare 50 mL of a 0.2 N solution is

MEDIUM
IMPORTANT

In the reaction 2CuSO4+4KI2Cu2I2+I2+2K2SO4, the equivalent weight of CuSO4 is

HARD
IMPORTANT

In the reaction Na2S2O3+4Cl2+5H2ONa2SO4+H2SO4+8HCl, the equivalent weight of Na2S2O3 is _____ (M is the molecular weight of Na2S2O3).

MEDIUM
IMPORTANT

x moles of potassium dichromate oxidises 1 mole of ferrous oxalate, in acidic medium. Here x is:

MEDIUM
IMPORTANT

Which amongst the following has the highest normality?

MEDIUM
IMPORTANT

For neutralization of one mol of NaOH mass of 70% H2SO4 required is: