Third Law of Thermodynamics
Third Law of Thermodynamics: Overview
This topic covers the concept of Third Law of Thermodynamics.
Important Questions on Third Law of Thermodynamics
Identify the correct statement regarding entropy:
What is residual entropy of the substance?
Calculate the entropy change for the following reaction at and pressure.
, the absolute entropy values () for and .
Write the statement of third law of thermodynamics.
Third law of thermodynamics helps in the calculation of the absolute entropy of a substance at any temperature ‘’.
The third law of thermodynamics states that, the entropy of a perfect crystal at a temperature of zero degree Celsius is equal to zero.
At what temperature is the entropy of a perfectly crystalline substance taken as zero?
State the third law of thermodynamics.
Why is it impossible for any substance to have an absolute entropy zero at temperature greater than ?
State third law of thermodynamics. What is its usefulness?
Which of the following allotropes of sulphur has maximum at ?
Among the following, the reaction that is accompanied by a decrease in the entropy is
Identify the correct statement regarding entropy.
Entropy is a measure of disorder. For perfect crystalline substances at , entropy becomes:
For a perfectly crystalline solid Cp,m = aT3 , where 'a' is constant. If Cp,m is at 10 K, molar entropy at 20 K is :
Which law of thermodynamics help in calculating entropy at different temperatures?
The entropy of a perfectly crystalline material is zero at . This statement matches with the-
The entropy of a perfectly crystalline material is zero at 0 K. This is statement of
