Selective Discharge of Ions

IMPORTANT

Selective Discharge of Ions: Overview

In this topic, we will learn about the selective discharge of ions in the process of electrolysis. We will also discuss the electrochemical series, which contains the metals in the order of their tendency to lose valence electron.

Important Questions on Selective Discharge of Ions

MEDIUM
IMPORTANT

Given that the standard electrode potentials  (E°) of metals are:

 K+/K=2.93V,Ag+/Ag=0.80V,Cu2+/Cu=0.34V,

 Mg2+/Mg=2.37V,Cr3+/Cr=0.74V,Fe2+/Fe=0.44V.

The increasing order of their reducing power is:

EASY
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Of the halide ions, the most powerful reducing agent is:

MEDIUM
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The standard reduction potential values of three metallic cations, X, Y and Z are 0.52,3.03 and1.18V respectively. The order of reducing power of the corresponding metals is:

MEDIUM
IMPORTANT

Standard electrode potential of three metals A, B and C are   + 0.5 V, 3.0 V and 1.2 V respectively. The reducing power of these metals are

EASY
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H2 cannot be displaced by

HARD
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The standard electrode potential of M2+/M is positive for

EASY
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Lower the position of an ion in an electrochemical series more easily it will get discharged at the respective electrode.

EASY
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How does nature of electrode affect selective discharge of ions.

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If a solution contains more than two cations and anions, the selective discharge of ions depends on electrochemical series.

EASY
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Define selective discharge of ions.

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Select the correct option, for the given standard Eo values of few redox couples:
Zn2+/Zn=-0.76V, Ag+/Ag=+0.80V, Cu2+/Cu=0.34V
 

EASY
IMPORTANT

Mark the correct statement based on the Eo values of redox couple of halogens given below
 EoI2/I-=+0.54V,EoBr2/Br-=+1.08V;EoCl2/Cl-=+1.36V.

MEDIUM
IMPORTANT

Which element can reduce Aluminium?

EASY
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Out of which of the following statements is true- 

Given the reduction potential data as-  EAg+/Ago=+0.8 V, ENi+2/Nio=- 0.25 V  .

EASY
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Among the following, which is the most reactive metal which displaces other metals from their salts in solution?

EZn/Zn2+0=+0.76V, EAg/Ag+0=-0.80V, 

ECu/Cu2+0=-0.34V, ECo/Co+20=0.28V

EASY
IMPORTANT

We have taken two electrode, with potential values: EMg2+/Mga=- 2.37 V and EbFe3+/Fe =-0.04 V. Which of the following will act as the best reducing agent:

MEDIUM
IMPORTANT

Identify the correct order of the metals in which they displace each other from solution of their salts:

EASY
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Which of the following can not displace H2?

EASY
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The decreasing order of reducing power of P, Q, R, S whose reduction potential are -2.90, +0.34, +1.20 and -0.76, is

EASY
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The more reactive the metal, the less likely the metal ions are to be discharged preferentially at the _____ during electrolysis.