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In which case, depression freezing point is equal to cryoscopic constant for water?

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A pressure cooker reduces cooking time for food because
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PtCl4·6H2O can exist as a hydrated complex. 1 molal aqueous solution has a depression in freezing point of 3.72°C. Assume, 100% ionization and Kf H2O=1.86 K mol-1 kg. Then the complex is:

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20 g of a binary electrolyte (molecular wt.=100 ) are dissolved in 500 g of water. The freezing point of the solution is  0.74°C, Kf=1.86 K molality1. The degree of ionization of the electrolyte is
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The ratio of elevation in boiling points of an aqueous solution containing 0.33 g of NaOH and another aqueous solution containing 3 g of glucose in the same volume is
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Van't Hoff factors of aqueous solutions of three different solutes, X, Y and Z are 1.8, 1.2 and 2.5, respectively. Hence, their order of molal concentration is

(Assume their freezing point is same.)

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Which of the following is not correct for an ideal solution?
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Which of the following is less than zero for ideal solutions?
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The boiling points of two miscible liquids, which do not form an azeotropic mixture, are close to each other. Their separation is best carried out by: