One mole of a real gas is subjected to heating at constant volume from $\left({\mathrm{P}}_1,{\mathrm{V}}_1,{\mathrm{T}}_1\right)$ state to $\left({\mathrm{P}}_2,{\mathrm{V}}_1,{\mathrm{T}}_2\right)$ state. Then it is subjected to irrerversible adiabatic compression against constant external pressure ${\mathrm{P}}_3 \mathrm{atm}$ till system reaches final state $\left({\mathrm{P}}_3,{\mathrm{V}}_2,{\mathrm{T}}_3\right)$. If the constant volume molar heat capacity of real gas is ${\mathrm{C}}_{\mathrm{V}}$. Find out correct expression for $∆\mathrm{H}$ from state $1$ to state $3$.