Valence Bond Theory-Orbital Overlap Concept

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Valence Bond Theory-Orbital Overlap Concept: Overview

This topic covers concepts, such as, Valence Bond Theory, Comparison of Sigma and Pi Bonds, Lateral Overlapping & Axial Overlapping etc.

Important Questions on Valence Bond Theory-Orbital Overlap Concept

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In which of the following molecules both phenyl rings are not coplanar ?

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Number of sigma bonds in   P 4 O 10 is :

 

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The correct statement for the structure of P4O10 is

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Which among the following represents zero overlap? 

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Which of the following has pπ-dπ bonding?

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Propyne molecule contains 6 sigma and _____ pi bonds.

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The sum of number of sigma and pi bonds formed between two carbon atoms in CaC2 are:

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Select the correct match : (consider z- axis as internuclear axis)

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Degree of unsaturation for given compound will be:

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Geometry of which of the following can't be explained using V.B.T. (pure overlapping)

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In which of the following species central atom forms compound in 2nd excited state, if excitation is considered to be true ?

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Which of the following overlapping results in formation of σ-bond, if z-axis is taken as internuclear axis ?

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C-C sigma and π bond in given molecule is:-

CH2=CCH2CH2CH32

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Assuming all non-hydrogen atoms undergo hybridization & following are various categories of orbital overlapping.

sp3-sp3 axial overlap σ Type -A

sp2-sp2 axial overlap σ Type -B

sp3-sp2 axial overlap σ Type -C

p-p lateral ovelap π Type -D

p-d lateral overlap π Type -E

Identify the species which contain only 2 of these types (from A to E) of overlapping of orbitals.

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The no. of σ and π bonds are present in given compound.

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Which of the following combinations of atomic orbitals can form only one type of covalent bond (out of σ, π & δ bond) :-

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Correct order of extent of axial overlapping is :-

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Number and type of bonds between two carbon atoms in CaC2 are

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Which of the following is not tetrahedral in shape?

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The number of σ and π bonds in allyl isocyanide are