Chemical Properties of Phenols
Chemical Properties of Phenols: Overview
This topic covers concepts such as Acidic Character of Phenols, Directive Nature of -OH group of Phenols, Chemical Properties of Phenols, Reaction of Phenols with Active Metals, Reaction of Phenol with NaOH, and Esterification Reaction of Phenols.
Important Questions on Chemical Properties of Phenols
Which of the following statements are true?
(i) Phenol is a stronger acid than alcohol.
(ii) Alcohols are comparatively more soluble in water than the corresponding hydrocarbons.

When sodium phenoxide is heated with carbon dioxide under pressure, sodium salicylate is obtained as major product. This on acidification given salicylic acid. This reaction is known as

The electrophile involved in the above reaction is

The electrophile involved in the above reaction is

The structure of the compound that gives a tribromo derivative on treatment with bromine water is

Choose the one, which posses highest acidic strength

Among the following phenols, the strongest is

The incorrect statement about is,

Which of the following are correct about ?

When nitrobenzenesulphonic acid and picric acid are treated with , the gases released respectively are

Which of the following will evolve on reaction with ?
Salicylic acid, Benzoic acid, Ascorbic acid, Phenol

In the following questions a statement of assertion followed by a statement of reason is given. Choose the correct answer out of the following choices.
Assertion : Phenols give and nitrophenol on nitration with conc. and mixture.
Reason : group in phenol is directing.

Assertion : Phenol is more reactive than benzene towards electrophilic substitution reaction.
Reason : In the case of phenol, the intermediate arenium ion is more stabilized by resonance.

Assertion: Phenol is more acidic than ethanol.
Reason: Phenoxide ion is resonance stabilized.

When phenol is treated with bromine water, the white precipitate formed is

The major product of the following reaction sequence is:

Acetoxy benzoic acid is commonly known as

Why is the ionization constant of phenol higher than that of ethanol?

Phenol on sulphonation at gives

Phenol is more acidic than that of ethanol because:
