Methods of Preparation of Haloalkanes and Haloarenes

In the presence of peroxide, hydrogen chloride and hydrogen iodide do not give anti-Markovnikoff’s addition with alkenes, because of the fact that:

Consider the following reaction



Identify the structure of the major product X.

Benzyl chloride  $\left(C_6{H}_{5}C{H}_{2}Cl\right)$ can be prepared from toluene by chlorination with –

The reaction condition leading to the best yield of ${\text{C}}_2{\text{H}}_5\text{Cl}$ are

How many products will be formed in above reaction.

For the given reaction how many products are optically active (all isomers):

Which of the following will not give haloderivative by addition of $\mathrm{HBr}$?

Chlorobenzene is prepared commercially by

The most polar compound among the following is:

When ethanol is treated with potassium bromide and concentrated ${\mathrm{H}}_2{\mathrm{SO}}_4$, _____ is produced.

Which reagent cannot be used to prepare an alkyl halide from alcohol?

Chlorobenzene is formed by reaction of chlorine with benzene in the presence of ${\mathrm{AlCl}}_3$. Which of the following species attacks the benzene ring in this reaction?

Alkyl halides are prepared from alcohols by treating with

Which of the following alcohols will yield the corresponding alkyl chloride on reaction with concentrated $\mathrm{HCl}$ at room temperature?

Which of the following can be used to prepare $3-$bromopropene?

The reaction, $\mathrm{RCl}+\mathrm{NaI}\stackrel{\mathrm{Acetone}}{\to }\mathrm{R}–\mathrm{I}+\mathrm{NaCl}$, is known as

The reaction of toluene with chlorine in the presence of iron and in the absence of light yields _____.