Preparations of Haloalkanes

IMPORTANT

Preparations of Haloalkanes: Overview

This topic covers concepts, such as, Preparations of Haloalkanes, Preparation of Haloalkanes From Alcohols, Finkelstein Reaction & Swarts Reaction etc.

Important Questions on Preparations of Haloalkanes

EASY
IMPORTANT

 The major product of the following reaction is: CH3CH2CH=CH2+HBr

EASY
IMPORTANT

Which of the following is an example of Sandmeyer reaction:

(i)

 C6H5N2+Cl-       +         KI   C6H5I + KCl + N2Benzene diazonium chloride   Iodobenzene

 (ii)

Question Image          

EASY
IMPORTANT

In the presence of peroxide, hydrogen chloride and hydrogen iodide do not give anti-Markovnikoff’s addition with alkenes, because of the fact that:

EASY
IMPORTANT

Consider the following reaction

Question Image

Identify the structure of the major product X.

EASY
IMPORTANT

The reaction condition leading to the best yield of   C2H5Cl are –

HARD
IMPORTANT

Which of the following cannot be prepared by Sandmeyer's reaction?

MEDIUM
IMPORTANT

Write the chemical reaction between potassium iodide and diazonium chloride.

EASY
IMPORTANT

Explain Gattermann reaction with an example of preparation chlorobenzene.

EASY
IMPORTANT

Write the reaction for preparation of iodo benzene through Gattermann reaction.

EASY
IMPORTANT

Explain Gattermann reaction with an example.

HARD
IMPORTANT

Aryl iodides can be prepared by reaction of arenes with iodine in the presence of an _____.(oxidising agent/reducing agent)

EASY
IMPORTANT

Chlorobenzene is formed by reaction of chlorine with benzene in the presence of AlCl3. Which of the following species attacks the benzene ring in this reaction?

EASY
IMPORTANT

Alkyl halides are prepared from alcohols by treating with

EASY
IMPORTANT

Which of the following alcohols will yield the corresponding alkyl chloride on reaction with concentrated HCl at room temperature?

EASY
IMPORTANT

The reaction, RCl+NaIAcetoneRI+NaCl, is known as

MEDIUM
IMPORTANT

The reaction of toluene with chlorine in the presence of iron and in the absence of light yields _____.

MEDIUM
IMPORTANT

In the preparation of ethyl iodide from ethane, this reaction is done in the presence of iodic acid which can reduce HI formed.

HARD
IMPORTANT

What happens in Finkelstein reactions?

MEDIUM
IMPORTANT

For the chemical reaction:
Question Image
The IUPAC name of the product is:

HARD
IMPORTANT

Which one of the following hydrocarbons when treated with chlorine will give only, single monochloro compound?