Isomerism

IMPORTANT

Isomerism: Overview

This topic covers concepts, such as, Isomerism, Types of Isomerism, Keto-Enol Tautomerism & Conditions for Keto-Enol Tautomerism etc.

Important Questions on Isomerism

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IMPORTANT

When an optically active compound is placed in a 10 dm tube, it is present 20 gm in a 200 mL solution rotates the PPL by 30o. Calculate the angle of rotation and specific angle of rotation if above solution diluted to 1 litre.

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Which of the following combinations amongst the four Fischer projections represents the same absolute configurations?

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MEDIUM
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On chlorination of propane, the number of products having the formula C3H6Cl2 is 

EASY
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Which of the following compound displays geometrical isomerism?

EASY
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The compound C2H5OC2H5 and CH3OCH2CH2CH3 are 

MEDIUM
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Which of the above compounds are enantiomers?

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Which of the above formula represent identical compounds?

EASY
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Which of the following cannot be written in an isomeric form?

HARD
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The structures shown here are related as being

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The compound with the above configuration is called:

HARD
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Molecular formula C3H6Br2 can have (including stereoisomer):

EASY
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Which of the following statements is true for a pair of diastereomers?

MEDIUM
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Which of the following sugars has the configuration (2S, 3R, 4R)?

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Stereoisomers differ from each other in what respect?

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Dextrorotatory α-pinene has a specific rotation α D 2 0 = +  51.3 . A sample of α-pinene containing both the enantiomers was found to have a specific rotation value α D 2 0 = +  30.8 . The percentages of the (+) and (-) enantiomers present in the sample are, respectively.

MEDIUM
IMPORTANT

Dextrorotatory α-pinene has a specific rotation α D 2 0 = +  51.3 . A sample of α-pinene containing both the enantiomers was found to have a specific rotation value α D 2 0 = +  30.8 . The percentages of the (+) and (-) enantiomers present in the sample are, respectively.

MEDIUM
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Relation between given pair is:

MEDIUM
IMPORTANT

Which of the following structures represents a chiral compound?

HARD
IMPORTANT

What common symmetry of elements if any are found in the stable chair conformer of trans-1, 2-dichlorocyclohexane?