Stereoisomerism

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Stereoisomerism: Overview

This topic covers concepts, such as, Stereoisomerism, Types of Stereoisomerism, Invertomerism & Calculation of Numbers of Stereoisomers etc.

Important Questions on Stereoisomerism

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When an optically active compound is placed in a 10 dm tube, it is present 20 gm in a 200 mL solution rotates the PPL by 30o. Calculate the angle of rotation and specific angle of rotation if above solution diluted to 1 litre.

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Which of the following combinations amongst the four Fischer projections represents the same absolute configurations?

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On chlorination of propane, the number of products having the formula C3H6Cl2 is 

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The number of optically active isomers observed in 1,2-dichlorobutane is:

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Which of the following compound displays geometrical isomerism?

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Number of possible isomers (stereoisomers) of D-glucose are:

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Which of the above compounds are enantiomers?

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Which of the following cannot be written in an isomeric form?

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The structures shown here are related as being

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How many stereoisomer of the following molecule are possible? HOOC.CH = C = CH.COOH

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The compound with the above configuration is called:

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The number of optically active compounds in the isomers of C4H9Br is:

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The number of isomers of C3H5Br3 (including stereoisomers):

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An optically pure compound X gave an α D 2 5 = + 2 0 . 0 . A mixture of X and its enantiomer Y gave α D 2 5 = + 1 0 . The ratio of X to Y in the mixture is:

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Which of the following statements is true for a pair of diastereomers?

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Which of the following sugars has the configuration (2S, 3R, 4R)?

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Which of the following statements must be true for two pure chiral isomers?

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Stereoisomers differ from each other in what respect?

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(+) - mandelic acid has a specific rotation of 158o. What would be the observed specific rotation of a mixture of 25% (-) - mandelic acid and 75% (+) - mandelic acid ?

MEDIUM
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(+) - mandelic acid has a specific rotation of 158o. What would be the observed specific rotation of a mixture of 25% (-) - mandelic acid and 75% (+) - mandelic acid?