Quantitative Analysis of Organic Compounds

IMPORTANT

Quantitative Analysis of Organic Compounds: Overview

This topic covers concepts, such as, Quantitative Analysis of Organic Compounds, Estimation of Carbon and Hydrogen, Reactions for Estimation of Oxygen & Expression for Estimation of Oxygen etc.

Important Questions on Quantitative Analysis of Organic Compounds

MEDIUM
IMPORTANT

In Carius method of estimation of halogens, 250 mg of an organic compound gave 141 mg of AgBr. The percentage of bromine in the compound is : (atomic mass Ag = 108; Br = 80)

EASY
IMPORTANT

Carius method is used to estimate which of the following compounds?

MEDIUM
IMPORTANT

Carius method is used for the estimation of halogen. 0.24 g of an organic compound gave 0.36 g of silver bromide. Percentage of bromine present in the compound is
 

MEDIUM
IMPORTANT

In quantitative analysis of carbon and hydrogen in an organic compound, let the mass of organic compound be m g, mass of water and carbon dioxide produced be m1 and m2 g respectively. The percentage of carbon is given as:

 

EASY
IMPORTANT

In which of the following methods the organic compound yields nitrogen gas by heating it with copper(II) oxide in the presence of carbon dioxide gas.

EASY
IMPORTANT

Using Duma's method for estimating nitrogen, 1 g of an organic compound X' gave 82 ml of nitrogen, collected at 27°C and 750 mm Hg pressure. If the aqueous tension at 27°C is 30 mm Hg pressure, then the percentage of nitrogen in the given compound X is

EASY
IMPORTANT

In Kjeldahl's method, organic 'N' is estimated as

HARD
IMPORTANT

Which of the following method is used for the estimation of oxygen in an organic compound?

HARD
IMPORTANT

The ammonia evolved from the treatment of 0.30 g of an organic compound for the estimation of nitrogen was passed in 100 mL of 0.1 M Sulphuric acid. The excess of acid required 20 mL of 0.5 M Sodium hydroxide solution for complete neutralization. The percentage of nitrogen in the organic compound is (Report the answer in the nearest integer).

MEDIUM
IMPORTANT

0.25 gm of organic compound on analysis by Dumas method produce 32 ml of nitrogen gas at STP. The percentage of nitrogen is?

MEDIUM
IMPORTANT

0.35 g of an organic compound in Duma's estimation for nitrogen gave 55 ml of nitrogen at 300 K and 715 mm pressure. If the aqueous tension at 300 K is 15 mm of Hg pressure, the percentage of nitrogen in the compound is:

HARD
IMPORTANT

Which of the following is correct?

MEDIUM
IMPORTANT

In Kjeldahl's method the gas evolved from 1.731 g sample of a fertilizer is passed into 50 ml of 0.20 N of H2SO4. 25 ml of 0.19 N NaOH are required for the titration of unused acid. The percentage of nitrogen by mass in fertilizer is :

HARD
IMPORTANT

The NH3 evolved from 0.5 gram of an organic compound in Kjeldahl method, neutralized 20 ml of M2H2SO4. Find the % of nitrogen :-

HARD
IMPORTANT

Estimation of oxygen in an organic compound can be made by.

HARD
IMPORTANT

Which of the following method is used for the estimation of oxygen?

HARD
IMPORTANT

An organic compound weighing 0.244 g on combustion with dry oxygen produces 0.616 g of CO2 and 0.108 g of H2O. Determine the percentage composition of the oxygen in compound.

HARD
IMPORTANT

During estimation of nitrogen present in an organic compound by Kjeldahl's method, the ammonia evolved from 0.5 g of the compound in Kjeldahl's estimation of nitrogen neutralized 10 mL of 1M H2SO4.​ The percentage of nitrogen in the compound is :

HARD
IMPORTANT

In the Kjeldahl's method for estimation of nitrogen present in a soil sample, ammonia evolved from 0.75 g of sample neutralized 10 mL of 1M H2SO4. The percentage of nitrogen in the soil is