Application of Electronic Effect

IMPORTANT

Application of Electronic Effect: Overview

This topic covers concepts, such as, Bond Parameters, Bond Order, Effect of Backbonding on Basic Strength of Compounds & Steric Inhibition of Resonance etc.

Important Questions on Application of Electronic Effect

MEDIUM
IMPORTANT

The abstraction of proton will be fastest from which carbon in the following compound?

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HARD
IMPORTANT

Which of the following statements would be true about the below compound?

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MEDIUM
IMPORTANT

Which of the following has longest C-O bond:

MEDIUM
IMPORTANT

Rank the following compounds in order of decreasing acidity of the indicated hydrogen :

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MEDIUM
IMPORTANT

The increasing order of basic strengths in their aqueous solutions is:

 NH3,CH3NH2,(CH3)2NH,(CH3)3N

EASY
IMPORTANT

Which of the following compound do not give the protonation reaction readily?

EASY
IMPORTANT

Amongst the following, the most basic compound is

MEDIUM
IMPORTANT

What is the correct order of acidity of the protons marked AD in the given compounds?

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HARD
IMPORTANT

Given below are two statements, one is labelled as Assertion A and the other is labelled as Reason R.

Assertion A : Order of acidic nature of the following compounds is  A > B > C.

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Reason R: Fluoro is a stronger electron withdrawing group than Chloro group.

In the light of the above statements, choose the correct answer from the options given below :

 

MEDIUM
IMPORTANT

Correct statements for the given reaction are:

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A. Compound ‘B’ is aromatic

B. The completion of above reaction is very slow

C. ‘A’ shows tautomerism

D. The bond lengths of C-C in compound B are found to be same

Choose the correct answer from the options given below.

EASY
IMPORTANT

The strongest acid from the following is

HARD
IMPORTANT

The correct order for acidity of the following hydroxyl compound is

(A) CH3OH

(B) CH33COH

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Choose the correct answer from the options given below:

MEDIUM
IMPORTANT

The descending order of acidity for the following carboxylic acid is-
(A) CH3COOH
(B) F3C-COOH
(C) ClCH2-COOH
(D) FCH2-COOH
(E) BrCH2-COOH
Choose the correct answer from the options given below:

MEDIUM
IMPORTANT

Assertion(A):  Acidic nature follows the order

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Reason: F is better electron withdrawing group than Cl.

EASY
IMPORTANT

In which of the following pair, the indicated bond has the greatest strength.

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MEDIUM
IMPORTANT

Arrange the acidic order of the following compounds in decreasing order

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MEDIUM
IMPORTANT

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The hydrogen removed in the Product A at the position

MEDIUM
IMPORTANT

Arrange marked atom in decreasing order of acidic strength

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HARD
IMPORTANT

Which of the following is most acidic?

EASY
IMPORTANT

Amongst the following, the total number of the compounds soluble in aqueous NaOH is:

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