Conductance in Electrolytic Solutions

IMPORTANT

Conductance in Electrolytic Solutions: Overview

This topic covers concepts such as Effect of Dilution on Specific Conductance, Equivalent Conductivity, Effect of Dilution on Equivalent Conductivity, Effect of Diluting a Strong Electrolyte on Electrolytic Conductivity, etc.

Important Questions on Conductance in Electrolytic Solutions

EASY
IMPORTANT

The molar conductivity of a 1.5 M solution of an electrolyte is found to be 138.9 S   c m 2   mo l 1 .  Calculate the conductivity of the solution.

MEDIUM
IMPORTANT

The molar conductivity of a 1.5 M solution of an electrolyte is found to be 138.9 S cm2 mol-1. Calculate the conductivity of the solution?

EASY
IMPORTANT

The relationship between the conductivity and the molar conductivity of a solution can be expressed as:

MEDIUM
IMPORTANT

How does the conductivity of a solution of acetic acid will vary if a solution of sodium hydroxide is added?

EASY
IMPORTANT

How does the conductivity of a solution of acetic acid will vary if a solution of sodium hydroxide is added?

HARD
IMPORTANT

The correct order of equivalent conductance at infinite dilution of LiCl, NaCl and KCl is:

MEDIUM
IMPORTANT

The resistance of a conductivity cell containing 0.001MKCl solution at 298 K is 1500 Ω. What is the cell constant if the conductivity of 0.001MKCl solution at 298 K is 0.146×10-3 Scm-1.

MEDIUM
IMPORTANT

The limiting molar conductivities of the given electrolytes at 298 K follow the order

λK+=735 S cm2 mol-1, λCl-=763 S cm2 mol-1, λCa2+=1190 S cm2 mol-1, λSO42-=160.0 S cm2 mol-1

MEDIUM
IMPORTANT

At a fixed concentration, the molar conductance of aqueous sodium hydroxide at 298 K is found to be10 ohm-1.cm2.mol-1. At infinite dilution and 298 K, its molar conductance is found to be 242 ohm-1.cm2.mol-1. Find the degree of ionization of sodium hydroxide at the same concentration and temperature.

EASY
IMPORTANT

If the conductivity of a 0.5MKCl solution at 298 K is 0.024 S.cm-1, then the molar conductivity of the solution would be ____ S.cm2·mol-1

MEDIUM
IMPORTANT

The molar conductivities of KCl, NaCl and KNO3 are 100, 120 and 90 cm2·mol-1, respectively. The molar conductivity of NaNO3 would be _____  cm2·mol-1

EASY
IMPORTANT

The conductivity of solutions of different electrolytes in the same solvent and at a given temperature differs due to charge and size of the _____.

EASY
IMPORTANT

Explain the effect of dilution on the molar conductivity of a strong electrolyte.

EASY
IMPORTANT

The degree of ionisation of a weak electrolyte increases

HARD
IMPORTANT

Among the following, the plot that correctly represents the conductometric titration of 0.05 M H2SO4 with 0.1 M NH4OH is

HARD
IMPORTANT

The molar conductivity of 0.02 M HCl solution is 407.2 S cm2 mol-1 at 25 °C. Its conductivity will be:

MEDIUM
IMPORTANT

The conductivity of 0.10M solution of KCl at 298K is 0.0129 S cm-1. Calculate its molar conductivity?

MEDIUM
IMPORTANT

The SI unit of molar conductivity is

HARD
IMPORTANT

The conductance of a 0.0015 M aqueous solution of a weak monobasic acid was determined by using a conductivity cell consisting of platinised Pt electrodes. The distance between the electrodes is 120 cm with an area of cross-section of 1 cm. The conductance of this solution was found to be 5×10-7 S. The pH of the solution is 4. The value of limiting molar conductivity (Λ°m) this weak monobasic acid in aqueous solution is Z×102 S cm2 mol-1.The value of Z is

MEDIUM
IMPORTANT

AgNO3 (aq) was added to an aqueous KCl solution gradually and the conductivity of the solution was measured. The plot of conductance Λ versus the volume of AgNO3 is