Titration

IMPORTANT

Titration: Overview

This topic covers concepts, such as, Acid-base Titration, Simple Titration, Back Titration of Acid and Base & Complexometric Titration etc.

Important Questions on Titration

MEDIUM
IMPORTANT

Number of moles of MnO4 is required to oxidise one mole of ferrous oxalate completely in an acidic medium will be:

MEDIUM
IMPORTANT

Ammonia evolved from the treatment of 0.30 g of an organic compound for the estimation of nitrogen was passed in 100 mL of 0.1 M sulphuric acid. The excess of acid required 20 mL of 0.5 M sodium hydroxide solution for complete neutralisation. The organic compound is

HARD
IMPORTANT

9.8 g of FeSO4NH42SO4·xH2O was dissolved in 250 mL of its solution. 20 mL of this solution required 20 mL of KMnO4 solution, containing 3.53 g of 90% pure KMnO4 dissolved per litre. Calculate x.

Round-off the answer to the nearest integer.

HARD
IMPORTANT

25 mL of a solution of Fe2+ ions require 32.45 mL of 0.0153 M K2Cr2O7 solution. What is the molarity of the Fe2+ solution?

(Report the answer by multiplying the value with 100 and rounding off to three significant figures)

EASY
IMPORTANT

Which of the following halogen oxides is used for the estimation of carbon monoxide in automobile exhaust gases?

HARD
IMPORTANT

0.1 N K2C2O4·3H2C2O4·4H2O solution reacts completely with 20ml 0.05M of KMnO4 solution in acidic medium. Another sample of same solution of K2C2O4. 3H2C2O4· 4H2O, having same volume is titrated with 18M NaOH solution, then find volume of NaOH solution (in ml) required. [Give your answer as sum of digit and Fill OMR sheet]

MEDIUM
IMPORTANT

The volume, in mL, of 0.02 M K2Cr2O7 solution required to react with 0.288 g of ferrous oxalate in acidic medium is ________. (Molar mass of Fe=56 g mol-1)

MEDIUM
IMPORTANT

A 20.0 mL solution containing 0.2 g impure H2O2 reacts completely with 0.316 g of KMnO4 in acid solution. The purity of H2O2(in %) is (mol. wt. of H2O2=34' mole wt. of KMnO4=158)

HARD
IMPORTANT

In a titration experiment, 10 mL of an FeCl2 solution consumed 25 mL of a standard K2Cr2O7 solution to reach the equivalent point. The standard K2Cr2O7 solution is prepared by dissolving 1.225 g of K2Cr2O7 in 250 mL water. The concentration of the FeCl2 solution is closest to

[Given : molecular weight of K2Cr2O7=294 g mol-1]

MEDIUM
IMPORTANT

The concentration of Na2S2O3.5H2O solution in grams per litre is y, 10 mL of which just de-colourised 15 mL of N20 iodine solution, calculate y4.65 value?

HARD
IMPORTANT

100 mL of 0.05 M CuSO4 (aq.) solution was electrolysed using inert electrodes by passing current till the pH of the resulting solution was 2. The solution after electrolysis was neutralized and then treated with excess KI and formed I2 was titrated with 0.04 M Na2S2O3. Calculate the required volume (in mL) of Na2S2O3.

MEDIUM
IMPORTANT

100 ml solution of 0.1 N HCl was titrated with 0.2 N NaOH solution. Find the volume of KOH 0.25 N that will be required for completing the titration, if the titration was discontinued after adding another 30 ml of NaOH solution. 

MEDIUM
IMPORTANT

A unit litre solution has a oxalic acid and carbonic acid dissolved in water. To neutralise 100 mL of  0.1M NaOH solution completely, 200 mL of the given solutuon is required.Another 200 mL of the same sample required 40 mL of 0.1 N of KMnO4. Which amongh the given statement is wrong?

HARD
IMPORTANT

What will be the molar mass of the dibasic acid if 1.575 g of a dibasic acid is neutralized by 25 mL of 1 M NaOH solution.?

EASY
IMPORTANT

What is the amount of NaOH required to neutralise 200 ml of 0.5M H2SO4 solution?

EASY
IMPORTANT

Find out the volume of 1M HCl required to react with a solution containing 0.5 mole of KOH and 1 mole of Na2CO3 in presence of phenolphthalein indicator.

MEDIUM
IMPORTANT

What will be the value of X if - 40 ml of 1 M HxA it required to completely react with 20 ml of 1 M Ca(OH)2. 

EASY
IMPORTANT

What is the molecular weight of acid if 10 mL of 0.1 M solution NaOH is completely neutralized by 25 mL of 3 g of dibasic acid in one litre solution?

EASY
IMPORTANT

A 50 mL 0.015 M Sodium Sulfite​ solution require 12 mL of an acidified potassium manganate solution for complete reaction. Volume of same permanganate solution that would be required to oxidize completely 0.12 g of Iron Oxalate is (Molecular weight of Fe = 56)

HARD
IMPORTANT

Excess of KI is allowed to react with a sample consisting of chocolate-brown powder of PbO2 and iodine liberated is reacted with N2H4 in another container. 1.12 litre of gas was liberated from this second container at STP .What is the volume of decimolar NaOH (in litres) required to dissolve PbO2 completely? (Assume all reactions are 100% complete)