Volumetric Analysis

IMPORTANT

Volumetric Analysis: Overview

This topic covers concepts such as Redox Reactions as a Basis for Titrations, Volumetric Analysis, Titration, Titer, Titrant, Equivalence Point, End Point in Titration, Redox Titration, Simple Redox Titration, Redox Back Titration, etc.

Important Questions on Volumetric Analysis

MEDIUM
IMPORTANT

Number of moles of MnO4 is required to oxidise one mole of ferrous oxalate completely in an acidic medium will be:

MEDIUM
IMPORTANT

The reaction of   H 2 S with    H 2 O 2 is an example of _____________ reaction

MEDIUM
IMPORTANT

The reaction of H2S with H2O2 is an example of _____________ reaction.

HARD
IMPORTANT

9.8 g of FeSO4NH42SO4·xH2O was dissolved in 250 mL of its solution. 20 mL of this solution required 20 mL of KMnO4 solution, containing 3.53 g of 90% pure KMnO4 dissolved per litre. Calculate x.

Round-off the answer to the nearest integer.

EASY
IMPORTANT

The volume used for a definite amount of unknown reagent at its equivalence point is known as _____.

EASY
IMPORTANT

Define titre value.

EASY
IMPORTANT

The n factor for dichromate ion in a redox reaction with Mohr's salt in an acidic medium is

HARD
IMPORTANT

I2 obtained from 0.1 mol of CuSO4 required 100 ml of 1 M hypo solution, hence, mole percentage of pure CuSO4 is

MEDIUM
IMPORTANT

What mass of Na2S2O3.5H2O is needed to make 500 cm3 of 0.200 N solution for the reaction :  2S2 O32-+ I2  S4 O62- + 2I-

MEDIUM
IMPORTANT

KMnO4 reacts with KI, in basic medium to form I2 and MnO2 . When 250 ml of  0.1 M KI solution is mixed with 250 ml of 0.02 M  KMnO4 in basic medium, what are the number of moles of I2 formed?

HARD
IMPORTANT

0.1 N K2C2O4·3H2C2O4·4H2O solution reacts completely with 20ml 0.05M of KMnO4 solution in acidic medium. Another sample of same solution of K2C2O4. 3H2C2O4· 4H2O, having same volume is titrated with 18M NaOH solution, then find volume of NaOH solution (in ml) required. [Give your answer as sum of digit and Fill OMR sheet]

EASY
IMPORTANT

The volume (in mL ) of 0.1 N NaOH required to neutralise 10 mL of 0.1 N phosphinic acid is __________ .

EASY
IMPORTANT

Consider titration of NaOH solution versus 1.25 M oxalic acid solution. At the end point following burette readings were obtained.
(i) 4.5 ml. (ii) 4.5 ml. (iii) 4.4 ml. (iv) 4.4 ml (v) 4.4 ml
If the volume of oxalic acid taken was 10.0 ml. then the molarity of the NaOH solution is ________ M. (Rounded-off to the nearest integer)

HARD
IMPORTANT

0.4 g mixture of NaOH, Na2CO3 and some inert impurities was first titrated with N10HCl using phenolphthalein as an indicator, 17.5 mL of HCl was required at the end point. After this methyl orange was added and titrated. 1.5 mL of same HCl was required for the next end point. The weight percentage of Na2CO3 in the mixture is_______ (Rounded-off to the nearest integer)

MEDIUM
IMPORTANT

The volume, in mL, of 0.02 M K2Cr2O7 solution required to react with 0.288 g of ferrous oxalate in acidic medium is ________. (Molar mass of Fe=56 g mol-1)

MEDIUM
IMPORTANT

A 20.0 mL solution containing 0.2 g impure H2O2 reacts completely with 0.316 g of KMnO4 in acid solution. The purity of H2O2(in %) is (mol. wt. of H2O2=34' mole wt. of KMnO4=158)

MEDIUM
IMPORTANT

Define "neutralisation".

HARD
IMPORTANT

In a titration experiment, 10 mL of an FeCl2 solution consumed 25 mL of a standard K2Cr2O7 solution to reach the equivalent point. The standard K2Cr2O7 solution is prepared by dissolving 1.225 g of K2Cr2O7 in 250 mL water. The concentration of the FeCl2 solution is closest to

[Given : molecular weight of K2Cr2O7=294 g mol-1]

EASY
IMPORTANT

When NH2CH2COOH.HCl is treated with NaOH,pH at first half equivalence point is 2.4 and the pH at second half equivalence point is 9.6. The pH at first equivalence point is -

MEDIUM
IMPORTANT

The concentration of Na2S2O3.5H2O solution in grams per litre is y, 10 mL of which just de-colourised 15 mL of N20 iodine solution, calculate y4.65 value?