Elevation in Boiling Point of the Solvent

IMPORTANT

Elevation in Boiling Point of the Solvent: Overview

This topic covers concepts, such as, Elevation of Boiling Point, Molal Boiling Point Elevation Constant, Molecular Mass of a Solute through Elevation of Boiling Point & Molal Boiling Point Elevation Constant Using Molar Heat of Vapourisation etc.

Important Questions on Elevation in Boiling Point of the Solvent

MEDIUM
IMPORTANT

A solution containing 8 g of a substance in 100 g of diethyl ether boils at 36.86°C,  whereas, pure ether boils at 35.60°C.

The molecular mass of the solute would be: (for etherKb=2.05Kkgmol1)

MEDIUM
IMPORTANT

18 g of glucose C6H12O6 dissolved in 1 kg of water is heated to boiling. The boiling point (in K) measured at 1 atm pressure is closest to [Ebullioscopic constant, Kb for water is 0.52 K kg mol-1. Consider absolute zero to be -273.15°C]

EASY
IMPORTANT

The molal boiling point elevation constant depends upon

MEDIUM
IMPORTANT

A solution of 122 g of benzoic-acid in 1000 g of benzene shows a boiling point elevation of 1.4°. If the solute is dimerized to an extent of 80%, the boiling point of pure benzene will be_________  (Molar enthalpy of vaporization of benzene =7.8kcal.mol-1 )

EASY
IMPORTANT

The elevation in boiling point of a solution of 10 g of a binary electrolyte (of molecular mass 100) in 100 g of water is ΔTb. Then the value of Kb for water is

EASY
IMPORTANT

Molal elevation constant is the elevation in boiling point produced by

EASY
IMPORTANT

The boiling point (in C) of 0.1 molal aqueous solution of CuSO4.5H2O at 1 bar is closest to: [Given: Ebullioscopic (molal boiling point elevation) constant of water, Kb=0.512 K kgmol-1

EASY
IMPORTANT

The molal elevation constant for water is 0.52. What will be the boiling point of 2 molar sucrose solution at 1 atm pressure? (Assume that the boiling point of pure water is 100 )

HARD
IMPORTANT

The boiling point of benzene is 353.23K. When 1.80 g of a non-volatile, non-ionisable solute was dissolved in 90g of benzene, the boiling point raised to 354.11 K. Calculate molar mass of the solute in gmol-1Kb for benzene= 2.53 K kg mol-1)

(Report your answer upto 1 decimal value)

EASY
IMPORTANT

The boiling point of 0.001 M aqueous solutions of NaCl, Na2SO4, K3PO4 and CH3COOH should follows the order.

MEDIUM
IMPORTANT

Latent heat of vaporization for a liquid solvent is 500 cal g-1. Let the boiling point be Tb K. Find the value of Kb of the solvent in K kg mol-1

MEDIUM
IMPORTANT

58.5 g of NaCl and 180 g of glucose were separately dissolved in 1000 mL of water. Identify the correct statement regarding the elevation of boiling point (b.pt.) of the resulting solutions.

EASY
IMPORTANT

The molal elevation constant is the ratio of the elevation in boiling point to:

MEDIUM
IMPORTANT

Which of the following aqueous solutions should have the highest boiling point?

EASY
IMPORTANT

The unit of an ebullioscopic constant is ______.

MEDIUM
IMPORTANT

Boiling point of a solvent is 80.2°C. When 0.419 g of the solute of molar mass 252.4 g mol-1 was dissolved in 75 g of the solvent, the boiling point of the solution was found to be 80.256°C. Find the molal elevation constant.

MEDIUM
IMPORTANT

Calculate the mass in grams of an impurity of molar mass 100 g mol-1 which would be required to raise the boiling point of 50 g of chloroform by 0.30 K(Kb for chloroform = 3.63 K kg mol-1)

EASY
IMPORTANT

If mass is expressed in gram then Kb is given by.

EASY
IMPORTANT

The determination of molar mass from elevation in boiling point is called as

EASY
IMPORTANT

When NaCl is added to water.