Ideal and Non-ideal Solutions

IMPORTANT

Ideal and Non-ideal Solutions: Overview

This topic covers concepts, such as, Non-Ideal Solutions, Non-Ideal Solutions with Positive Deviation from Raoult's Law, Ideal Solution & Fractional Distillation of Ideal Solution etc.

Important Questions on Ideal and Non-ideal Solutions

EASY
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Use the phase diagram below to explain how you can obtain a pure sample of B from a mixture M by successively boiling and condensing the ideal liquid mixture.

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MEDIUM
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Fractional distillations can not separate an ideal mixture.

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Nan-ideal solutions are separated by fractional distillation. What are negatively deviated non-ideal solutions? Give examples.

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How does the non-ideal solutions separated?

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The minimum boiling azeotrope have _____ from Raoult's law.

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The negative deviation from Raoult's Law is observed when, the vapour pressure of the components is less than what is expected.

MEDIUM
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Which of the following mixtures of solutions follow the conditions  ΔmixH<0 and ΔmixV<0 ?
(i) Nitric acid + Water
(ii) Acetic acid + Pyridine
(iii) Ethanol + Water
(iv) Carbon tetra chloride + Chloroform

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Which of the following is not an ideal solution?

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An ideal solution is that which

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Volume change when two volatile liquids mix to form an ideal solution:
 

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Write definition of azeotropic mixture _____

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A mixture of 250 ml of A and 250 ml of B shows a positive deviation from ideality. A second mixture of 250 ml of A and 250 ml of C shows a negative deviation from ideality. Which of the following statements is true?

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If liquid A and B forms an ideal solution, then the:-

EASY
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Intermolecular forces between two benzene molecules are nearly of same strength as those between two toluene molecules. For a mixture of benzene and toluene, which of the following are not true?

MEDIUM
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On the basis of information given below mark the correct option.
Information : On adding acetone to methanol some of the hydrogen bonds between methanol molecules break.

MEDIUM
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If two liquids A and B form minimum boiling azeotrope at some specific composition then _____.

MEDIUM
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Considering the formation, breaking and strength of hydrogen bond, predict which of the following mixtures will show a positive deviation from Raoult’s law?

HARD
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The property of an ideal solution is :

HARD
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Which liquid pair solution show positive deviations?

MEDIUM
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Ethyl chloride mixed with ethyl bromide, which of the following is appropriate?