Van't Hoff's Factor
Van't Hoff's Factor: Overview
This topic covers concepts, such as Abnormal Molar Mass, Van't Hoff's Factor, Van't Hoff Correction Factor for Dissociation of Solute Particles, and Determination of Degree of Dissociation Using Van't Hoff's Factor.
Important Questions on Van't Hoff's Factor
The Van't Hoff factor for a compound which undergo dissociation in one solvent and association in other solvents is respectively

The depression in the freezing point for urea, glucose, and sodium chloride in the ratio


Four solutions of with the concentrations and are available. The maximum value of Van't Hoff factors, correspond to

Relative decrease in vapour pressure is for a solution containing in , therefore is ionised at the extent of

If the osmotic pressure of a 0.010 M aqueous solution of sucrose at is 0.25 atm, then the osmotic pressure of a 0.010 M aqueous solution of NaCl at is

What are the minimum values of the Van't Hoff factors in a solute undergoing dimerisation and trimerisation?

Which of the following is the correct value of degree of association in terms of van't Hoff factor () is:

Which of the following is the correct value of degree of dissociation in terms of van't Hoff factor () is:

The value of observed and calculated molecular weight of calcium nitrate are and . The degree of dissociation of will be:-

The partial dissociation appears to be a major factor in determining the properties of weak electrolytes and the degree of dissociation for weak electrolyte at dilution v is given by . The strong electrolytes on the other hand do not obey this relation and the variation of molar conductivity for strong electrolytes is given by .
The graph plotted for log ()vs. log , where i is van't Hoff factor for uni-univalent electrolyte and , is its molar conductivity at concentration c does not show the following characteristics:

The van’t Hoff factor for a compound which undergoes dissociation in one solvent and association in another solvent is respectively

Which of the following aqueous solutions will exert highest osmotic pressure?

Which of the following solutions will exhibit highest osmotic pressure?

Arrange the following in increasing order of their boiling point.

What will be the boiling point of the final solution if one litre solution of 1 molar is mixed with 1 litre solution of 1 molar ?
Assume 100% ionisation of and in the solvent and molality = molarity
Given: of the solvent is , boiling point of the pure solvent is 400 K.

A complex containing , and is ionised. Giving .
Thus, what is the following complex?

solution of glucose is isotonic with a solution of sodium sulphate at the same temperature. The apparent percentage dissociation of is

A salt has van't Hoff factor equal to , then what will be its degree of dissociation in water?

The freezing point of water of a solution is depressed by . The freezing point of solution of urea is depressed by:
