Empirical and Molecular Formulae
Empirical and Molecular Formulae: Overview
This topic covers concepts, such as, Types of Chemical Formulae, Empirical Formula, Molecular Formula, Steps Involved in Determination of Empirical Formula of a Compound & Relation between Empirical Formula and Molecular Formula etc.
Important Questions on Empirical and Molecular Formulae
An organic compound A contains carbon, hydrogen and the rest is oxygen. The molecular mass of the compound is . It does not reduce Tollen’s reagent but forms an addition product with sodium hydrogen sulphite and gives positive iodoform test. On vigorous oxidation it gives ethanoic and propanoic acids. The compound A is:

An organic compound contains carbon, hydrogen and oxygen. Its elemental analysis gave and . The empirical formula of the compound would be:

An organic compound containing gave on analysis Its empirical formula would be:

An organic compound containing gave the following analysis:
Its empirical formula would be:

In a compound C, H, N atoms are present in the ratio 9 : 1 : 3.5 by mass. If molecular mass of the compound is 108, then molecular formula of the compound is

In a compound C, H, N atoms are present in the ratio 9 : 1 : 3.5 by mass. If molecular mass of the compound is 108, then molecular formula of the compound is

An organic compound having molecular mass 60 u is found to contain rest being oxygen. On heating, it gives along with solid residue. The solid residue gives violet colour with alkaline copper sulphate solution. The compound is

An organic compound , containing and , on analysis gives carbon, hydrogen and nitrogen. on boiling with gives of and a salt, which on acidification gives a monobasic nitrogen-free acid . The silver salt of contains silver. The structures of and are.

A certain hydrocarbon was found to contain percent carbon and percent hydrogen. This compound consumes equivalent of hydrogen to give a saturated hydrocarbon . of hydrocarbon just decolourised of a percent solution (by weight) of Compound , on oxidation with concentrated gave compound (molecular formula, ) and acetic acid. The compound could easily be prepared by the action of acidic aqueous mercuric sulphate on butyne. The molecular formula of are.

If two compounds have the same empirical formula but different molecular formulae, they must have

To check the principle of multiple proportions, a series of pure binary compounds were analysed and their composition is tabulated below. The correct option(s) is(are)
Compound | Weight of | Weight of |

The pair of species having same percentage of carbon is -

A compound contains hydrogen, carbon and chlorine. What is its empirical formula?

What is the empirical formula of the salt?

In an ionic compound moles ratio of cation to anion is . If atomic masses of metal and non-metal respectively are and , then correct statement is:

Which of the following is true about empirical formula and molecular formula?

For fixed mass of nitrogen in its two oxides and mass ratio of oxygen is . If in of combines with of oxygen, then empirical formula of will be:

A compound contains atoms of , atoms of and atoms of . Find the empirical formula of compound:

Determine the simplest formula of a compound containing of element (atomic mass ) and of the element (atomic mass ) by weight.

The empirical formula as well as molecular formula of water is .
